CID 6367285

Base Information

• Chemical Name: CID 6367285
• CAS No.: 54008-40-1
• Molecular Formula: C12H2F10Ge
• Molecular Weight: 408.722
• DSSTox Substance ID: DTXSID40389043
• Mol file: 54008-40-1.mol

Synonyms:54008-40-1;CTK1E3441;DTXSID40389043

Chemical Property of CID 6367285

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 2
• Exact Mass: 407.9052094
• Heavy Atom Count: 23
• Complexity: 345

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1(=C(C(=C(C(=C1F)F)[Ge]C2=C(C(=C(C(=C2F)F)F)F)F)F)F)F

Technology Process of CID 6367285

There total 12 articles about CID 6367285 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

tris(pentafuorophenyl)germane (42371-50-6) → bis-(pentafluoro phenyl) germane (54008-40-1)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; at 50°C, 2 h;

DOI:10.1016/S0022-328X(00)89685-0

Reference yield: 86.2%

lithium aluminium tetrahydride (16853-85-3) + bis(pentafluorophenyl)germanium dibromide (10177-65-8) → bis-(pentafluoro phenyl) germane (54008-40-1)

Guidance literature:

In toluene; addition of ether to a mixture of C6F5GeBr3 and LiAlH4 in toluene; cooling at 0°C;;

Reference yield: 75.0%

bis(pentafluorophenyl)germanium dibromide (10177-65-8) + AlH4Li(1-)*Li(1+) → bis-(pentafluoro phenyl) germane (54008-40-1)

Guidance literature:

bis(pentafluorophenyl)germanium dibromide; AlH₄Li^(1-)*Li⁽¹⁺⁾; In diethyl ether; toluene; at 20 ℃; for 1h; Schlenk technique; Inert atmosphere;

With hydrogenchloride; ethyl acetate; In diethyl ether; water; toluene; for 1h; Schlenk technique; Inert atmosphere;

DOI:10.1021/om4008218

upstream raw materials:

lithium aluminium tetrahydride

bis(pentafluorophenyl)germanium dibromide

Triethylgerman

tris(pentafuorophenyl)germane

Downstream raw materials:

1,1,1,3,3,3-Hexaethyl-2,2-bis(pentafluorphenyl)trigerman

(C₆F₅)2Ge(H)Sn(C₂H₅)3

hexakis-(pentafluoro phenyl) digermoxane

Chloro[tris(perfluorophenyl)]-germane

Refernces