Silane, (1,1-dimethylethyl)diphenyl[[(2R,3S)-3-[[(2S,3R)-3-undecyloxiranyl]meth yl]oxiranyl]methoxy]-

Base Information

Chemical Name:Silane, (1,1-dimethylethyl)diphenyl[[(2R,3S)-3-[[(2S,3R)-3-undecyloxiranyl]meth yl]oxiranyl]methoxy]-
CAS No.:556783-93-8
Molecular Formula:C33H50O3Si
Molecular Weight:522.844
Hs Code.:

Synonyms:

Suppliers and Price of Silane, (1,1-dimethylethyl)diphenyl[[(2R,3S)-3-[[(2S,3R)-3-undecyloxiranyl]meth yl]oxiranyl]methoxy]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Silane, (1,1-dimethylethyl)diphenyl[[(2R,3S)-3-[[(2S,3R)-3-undecyloxiranyl]meth yl]oxiranyl]methoxy]-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Silane, (1,1-dimethylethyl)diphenyl[[(2R,3S)-3-[[(2S,3R)-3-undecyloxiranyl]meth yl]oxiranyl]methoxy]-

There total 8 articles about Silane, (1,1-dimethylethyl)diphenyl[[(2R,3S)-3-[[(2S,3R)-3-undecyloxiranyl]meth yl]oxiranyl]methoxy]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

: 556783-90-5
(2R,3S,5Z)-1-(tert-butyldiphenylsilyloxy)-cis-2,3-epoxy-5-heptadecene

: 556783-93-8
(2R,3S,5S,6R)-1-(tert-butyldiphenylsilyloxy)-cis-2,3-cis-5,6-diepoxyheptadecane

: 556783-92-7
(2R,3S,5R,6S)-1-(tert-butyldiphenylsilyloxy)-cis-2,3-cis-5,6-diepoxyheptadecane

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 5h;
DOI:10.1002/ejoc.200390186

Reference yield:

: 87770-83-0
(Z)-4-((tert-butyldiphenylsilyl)oxy)but-2-en-1-ol

: 556783-93-8
(2R,3S,5S,6R)-1-(tert-butyldiphenylsilyloxy)-cis-2,3-cis-5,6-diepoxyheptadecane

Guidance literature:: Multi-step reaction with 6 steps

1.1: 94 percent / MCPBA / CH₂Cl₂ / 6 h / 20 °C

2.1: 49 percent / Lipase PS-D / diethyl ether / 4 h / 20 °C

3.1: 99 percent / K₂CO₃ / methanol / 1 h / 0 °C

4.1: nBuLi / hexane; tetrahydrofuran / 0.5 h / -78 °C

4.2: Tf₂O / hexane; tetrahydrofuran / 0.5 h / -78 °C

4.3: 80 percent / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 1.5 h / -78 °C

5.1: 95 percent / H₂ / 5 percent Pd-CaCO₃-Pb₂(+) / cyclohexane / 3 h / 20 °C

6.1: 48 percent / MCPBA / CH₂Cl₂ / 5 h / 20 °C

With n-butyllithium; lipase PS-D; hydrogen; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; Pd-CaCO₃-Pb₂(+); In tetrahydrofuran; methanol; diethyl ether; hexane; dichloromethane; cyclohexane;
DOI:10.1002/ejoc.200390186

Reference yield:

: 117901-01-6
((2S,3R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol

: 556783-93-8
(2R,3S,5S,6R)-1-(tert-butyldiphenylsilyloxy)-cis-2,3-cis-5,6-diepoxyheptadecane

Guidance literature:: Multi-step reaction with 3 steps

1.1: nBuLi / hexane; tetrahydrofuran / 0.5 h / -78 °C

1.2: Tf₂O / hexane; tetrahydrofuran / 0.5 h / -78 °C

1.3: 80 percent / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 1.5 h / -78 °C

2.1: 95 percent / H₂ / 5 percent Pd-CaCO₃-Pb₂(+) / cyclohexane / 3 h / 20 °C

3.1: 48 percent / MCPBA / CH₂Cl₂ / 5 h / 20 °C

With n-butyllithium; hydrogen; 3-chloro-benzenecarboperoxoic acid; Pd-CaCO₃-Pb₂(+); In tetrahydrofuran; hexane; dichloromethane; cyclohexane;
DOI:10.1002/ejoc.200390186