(E,2R,4R)-2-((2S,3S,4S,5S)-2,4-Dihydroxy-3,5-dimethyl-6-((2S)-3-oxopentan-2-yl)oxan-2-yl)-4,6-dimethyl-non-6-en-3-one

Base Information

Chemical Name:(E,2R,4R)-2-((2S,3S,4S,5S)-2,4-Dihydroxy-3,5-dimethyl-6-((2S)-3-oxopentan-2-yl)oxan-2-yl)-4,6-dimethyl-non-6-en-3-one
CAS No.:87697-98-1
Molecular Formula:C₂₃H₄₀O₅
Molecular Weight:396.568
Hs Code.:
Wikidata:Q110186485
Metabolomics Workbench ID:175389

Synonyms:Denticulatin A;(E,2R,4R)-2-((2S,3S,4S,5S)-2,4-Dihydroxy-3,5-dimethyl-6-((2S)-3-oxopentan-2-yl)oxan-2-yl)-4,6-dimethyl-non-6-en-3-one;87697-98-1

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E,2R,4R)-2-((2S,3S,4S,5S)-2,4-Dihydroxy-3,5-dimethyl-6-((2S)-3-oxopentan-2-yl)oxan-2-yl)-4,6-dimethyl-non-6-en-3-one

Chemical Property:

Vapor Pressure:1.62E-13mmHg at 25°C
Boiling Point:531.5°Cat760mmHg
Flash Point:171.7°C
Density:1.024g/cm³
XLogP3:4.6
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:9
Exact Mass:396.28757437
Heavy Atom Count:28
Complexity:584

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCC=C(C)CC(C)C(=O)C(C)C1(C(C(C(C(O1)C(C)C(=O)CC)C)O)C)O
Isomeric SMILES:CC/C=C(\C)/C[C@@H](C)C(=O)[C@@H](C)[C@@]1([C@H]([C@H]([C@H](C(O1)[C@H](C)C(=O)CC)C)O)C)O

Technology Process of (E,2R,4R)-2-((2S,3S,4S,5S)-2,4-Dihydroxy-3,5-dimethyl-6-((2S)-3-oxopentan-2-yl)oxan-2-yl)-4,6-dimethyl-non-6-en-3-one

There total 80 articles about (E,2R,4R)-2-((2S,3S,4S,5S)-2,4-Dihydroxy-3,5-dimethyl-6-((2S)-3-oxopentan-2-yl)oxan-2-yl)-4,6-dimethyl-non-6-en-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 140870-63-9
(E)-(2S,4R,6R)-2-[(4S,5S,6R)-2,2-Di-tert-butyl-5-methyl-6-((S)-1-methyl-2-oxo-butyl)-[1,3,2]dioxasilinan-4-yl]-4,6,8-trimethyl-undec-8-ene-3,5-dione

: 87758-52-9
Denticulatin B

: 87697-98-1
Denticulatin A

Guidance literature:: With pyridine hydrogenfluoride; In tetrahydrofuran; for 4h; Yields of byproduct given; Ambient temperature;
DOI:10.1016/S0040-4020(97)00617-0

Reference yield: 58.0%

: 132566-03-1
(2S,4S,6R,8E)-2-<(2S,3S,4R,5S,6S)-6-Ethyl-6-hydroxy-4-(p-methoxybenzyloxy)-3,5-dimethyl-tetrahydro-2H-pyran-2-yl>-4,6,8-trimethyl-8-undecen-3,5-dione

: 87697-98-1,87758-52-9
(-)-Denticulatin A and B

Guidance literature:: With ammonia; lithium; lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.5h;

Reference yield: 51.0%

: (E)-(2S,6R)-2-[(4S,5S,6R)-2,2-Di-tert-butyl-5-methyl-6-((S)-1-methyl-2-oxo-butyl)-[1,3,2]dioxasilinan-4-yl]-4,6,8-trimethyl-undec-8-ene-3,5-dione

: 87697-98-1,87758-52-9
Denticulatine A/B

Guidance literature:: With pyridine hydrogenfluoride; In tetrahydrofuran; pyridine; for 4h; Ambient temperature;
DOI:10.1016/0040-4039(95)00787-D