Neotruxinic acid

Base Information

• Chemical Name: Neotruxinic acid
• CAS No.: 490-16-4
• Molecular Formula: C₁₈H₁₆O₄
• Molecular Weight: 296.323
• Mol file: 490-16-4.mol

Synonyms:

Chemical Property of Neotruxinic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Neotruxinic acid

There total 66 articles about Neotruxinic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

(E)-3-phenylacrylic acid (140-10-3) → β-truxinic acid (528-34-7,898816-27-8) + (1R,2R,3S,4S)-3,4-Diphenyl-cyclobutane-1,2-dicarboxylic acid (490-16-4,528-32-5,528-33-6,528-34-7,528-35-8,528-36-9,4482-52-4)

Guidance literature:

With (2r,4s,5r)-2,4,5,6-tetrakis(3,6-di-tert-butyl-9H-carbazol-9-yl)isophthalonitrile; In 1,4-dioxane; at 20 ℃; for 36h; diastereoselective reaction; Inert atmosphere; Irradiation;

DOI:10.1039/c9ob02735a

Reference yield:

(E)-3-phenylacrylic acid (140-10-3) → cis-cinnamic acid (140-10-3,621-82-9,102-94-3) + β-truxinic acid (528-34-7,898816-27-8) + (1R,2R,3S,4S)-3,4-Diphenyl-cyclobutane-1,2-dicarboxylic acid (490-16-4,528-32-5,528-33-6,528-34-7,528-35-8,528-36-9,4482-52-4)

Guidance literature:

With hydrotalcite clay; In water; for 4h; Product distribution; Irradiation; various aluminium ion content in hydrotalcite;

DOI:10.1039/cc9960002027

Reference yield:

(E)-3-Phenyl-acrylic acid; compound with (1R,2R)-cyclohexane-1,2-diamine → cis-cinnamic acid (140-10-3,621-82-9,102-94-3) + δ-truxinic acid (490-16-4,528-32-5,528-33-6,528-34-7,528-35-8,528-36-9,4482-52-4) + ε-truxillic acid trans-cyclohexane-1,2-diamine

Guidance literature:

for 10h; Irradiation;

DOI:10.1016/0040-4039(95)01209-Z

upstream raw materials:

benzaldehyde

(E)-3-phenylacrylic acid

cinnamic anhydride

cis-cyclohexane-1,2-diamine

Downstream raw materials:

trans,trans-1,4-Diphenyl-1,3-butadiene

(1Z,3E)-1,4-diphenylbuta-1,3-diene

dimethyl μ-truxinate

3c,4c-diphenyl-cyclobutane-1r,2c-dicarboxylic acid