1-Methyl-2-[(1-oxoallyl)oxy]ethyl acetoacetate

Base Information

Chemical Name:1-Methyl-2-[(1-oxoallyl)oxy]ethyl acetoacetate
CAS No.:29818-16-4
Molecular Formula:C₁₀H₁₄O₅
Molecular Weight:214.218
Hs Code.:
European Community (EC) Number:249-877-3
DSSTox Substance ID:DTXSID60863092
Nikkaji Number:J286.968C
Mol file:29818-16-4.mol

Synonyms:29818-16-4;EINECS 249-877-3;1-METHYL-2-[(1-OXOALLYL)OXY]ETHYL ACETOACETATE;1-Methyl-2-((1-oxoallyl)oxy)ethyl acetoacetate;SCHEMBL271472;DTXSID60863092;1-[(Prop-2-enoyl)oxy]propan-2-yl 3-oxobutanoate;3-Oxobutanoic acid 1-methyl-2-[(1-oxo-2-propenyl)oxy]ethyl ester;Butanoic acid, 3-oxo-, 1-methyl-2-((1-oxo-2-propenyl)oxy)ethyl ester

Suppliers and Price of 1-Methyl-2-[(1-oxoallyl)oxy]ethyl acetoacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 1-Methyl-2-[(1-oxoallyl)oxy]ethyl acetoacetate

Chemical Property:

Vapor Pressure:0.000809mmHg at 25°C
Boiling Point:305.7°Cat760mmHg
Flash Point:132.3°C
PSA：69.67000
Density:1.109g/cm³
LogP:0.62640
XLogP3:0.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:8
Exact Mass:214.08412354
Heavy Atom Count:15
Complexity:269

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(COC(=O)C=C)OC(=O)CC(=O)C

Technology Process of 1-Methyl-2-[(1-oxoallyl)oxy]ethyl acetoacetate

There total 2 articles about 1-Methyl-2-[(1-oxoallyl)oxy]ethyl acetoacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 5394-63-8
2,2,6-trimethyl-4H-1,3-dioxin-4-one

: 291530-55-7,32029-53-1
2-(S)-hydroxypropyl propenoate

: 290834-74-1,29818-16-4
2-(S)-(1,3-dioxobutyl)oxypropyl propenoate

Guidance literature:: In xylene; for 2h; Heating;
DOI:10.1016/S0957-4166(00)00132-4

Reference yield:

: 290834-73-0
2-(S)-(tetrahydropyranyl)oxypropyl propenoate

: 290834-74-1,29818-16-4
2-(S)-(1,3-dioxobutyl)oxypropyl propenoate

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / aq. HCl / methanol / 0.5 h / 20 °C

2: 89 percent / xylene / 2 h / Heating

With hydrogenchloride; In methanol; xylene; 1: Hydrolysis / 2: Acylation;
DOI:10.1016/S0957-4166(00)00132-4