4-Npmgp

Base Information

Chemical Name:4-Npmgp
CAS No.:101455-34-9
Molecular Formula:C₁₈H₂₅NO₁₆P*Na
Molecular Weight:565.357
Hs Code.:
Mol file:101455-34-9.mol

Synonyms:4-nitrophenyl-(alpha)-mannopyranoside 6-(alpha-glucopyranosyl phosphate);4-NPMGP

Suppliers and Price of 4-Npmgp

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 4-Npmgp

Chemical Property:

Vapor Pressure:2.65E-26mmHg at 25°C
Boiling Point:790°Cat760mmHg
Flash Point:431.6°C
PSA：280.69000
Density:1.8g/cm³
LogP:-2.76210
XLogP3:-3.6
Hydrogen Bond Donor Count:8
Hydrogen Bond Acceptor Count:16
Rotatable Bond Count:8
Exact Mass:543.09892074
Heavy Atom Count:36
Complexity:777

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=CC=C1[N+](=O)[O-])OP(=O)(OCC2C(C(C(C(O2)O)O)O)O)OC3C(C(C(C(O3)CO)O)O)O
Isomeric SMILES:C1=CC(=CC=C1[N+](=O)[O-])OP(=O)(OC[C@@H]2[C@H]([C@@H]([C@@H]([C@H](O2)O)O)O)O)O[C@@H]3[C@@H]([C@H]([C@@H]([C@H](O3)CO)O)O)O

Technology Process of 4-Npmgp

There total 12 articles about 4-Npmgp which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 101455-31-6,101455-33-8
p-nitrophenyl 2,3,4-tri-O-benzoyl-α-D-mannopyranoside 6-(triethylammonium 2,3,4,6-tetra-O-acetyl-α-D-galactopyranosyl phosphate)

: 101455-34-9,101455-35-0
p-nitrophenyl α-D-mannopyranoside 6-(sodium α-D-galactopyranosyl phosphate)

Guidance literature:: With methanol; water; triethylamine; at 4 ℃; for 16h;
DOI:10.1016/S0008-6215(00)90697-9

Reference yield: 83.0%

: 101455-31-6,101455-33-8
p-nitrophenyl 2,3,4-tri-O-benzoyl-α-D-mannopyranoside 6-(triethylammonium 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl phosphate)

: 101455-34-9,101455-35-0
p-nitrophenyl α-D-mannopyranoside 6-(sodium α-D-glucopyranosyl phosphate)

Guidance literature:: With methanol; water; triethylamine; at 4 ℃; for 16h;
DOI:10.1016/S0008-6215(00)90697-9

Reference yield:

: 334700-80-0
(2R,3S,4S,5S,6R)-2-[(4-Methoxy-phenyl)-diphenyl-methoxymethyl]-6-(4-nitro-phenoxy)-tetrahydro-pyran-3,4,5-triol

: 101455-34-9,101455-35-0
p-nitrophenyl α-D-mannopyranoside 6-(sodium α-D-glucopyranosyl phosphate)

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine / 5 h / Ambient temperature

2: 80percent aq. AcOH / 20 h / Ambient temperature

3: 68 percent / 3-nitro-1-(2,4,6-triisopropylbenzenesulfonyl)-1,2,4-triazole / pyridine / 18 h / 37 °C / var. reag.: DCC

4: 83 percent / Et₃N, MeOH, H₂O / 16 h / 4 °C

With pyridine; methanol; water; acetic acid; 1-(2,4,6-triisopropylbenzenesulfonyl)-3-nitro-1,2,4-triazole; triethylamine; In pyridine;
DOI:10.1016/S0008-6215(00)90697-9