1,3-bis[(aminooxy)methyl]benzene

Base Information

• Chemical Name: 1,3-bis[(aminooxy)methyl]benzene
• CAS No.: 30777-80-1
• Molecular Formula: C8H12 N2 O2 . 2 Cl H
• Molecular Weight: 241.117
• Mol file: 30777-80-1.mol

Synonyms:Hydroxylamine,O,O'-(m-phenylenedimethylene)bis-, dihydrochloride (8CI); Hydroxylamine,O,O'-[1,3-phenylenebis(methylene)]bis-, dihydrochloride (9CI)

Chemical Property of 1,3-bis[(aminooxy)methyl]benzene

Chemical Property:

• Vapor Pressure: 9.37E-06mmHg at 25°C
• Boiling Point: 228.1°Cat760mmHg
• Flash Point: 83.6°C
• Density: g/cm³

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-bis[(aminooxy)methyl]benzene

There total 2 articles about 1,3-bis[(aminooxy)methyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

N,N'-m-phenylenedimethoxy-bis-phthalimide (30777-93-6) → m-Methyloxyamin-benzyloxyamin*Hydrochlorid (30777-80-1)

Guidance literature:

With hydrogenchloride; hydrazine; In ethanol; Heating;

DOI:10.1021/ja00047a057

Reference yield:

1,3-bis-(bromomethyl)benzene (626-15-3) → m-Methyloxyamin-benzyloxyamin*Hydrochlorid (30777-80-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 66 percent / Et₃N / acetonitrile / Heating

2: 86 percent / H₂NNH₂, HCl / ethanol / Heating

With hydrogenchloride; triethylamine; hydrazine; In ethanol; acetonitrile;

DOI:10.1021/ja00047a057

upstream raw materials:

N,N'-m-phenylenedimethoxy-bis-phthalimide

1,3-bis-(bromomethyl)benzene