((m-Tolyloxy)methyl)oxirane

Base Information

• Chemical Name: ((m-Tolyloxy)methyl)oxirane
• CAS No.: 2186-25-6
• Molecular Formula: C10H12 O2
• Molecular Weight: 164.204
• Hs Code.: 2910900090
• European Community (EC) Number: 218-575-3
• NSC Number: 86974
• DSSTox Substance ID: DTXSID40862861
• Nikkaji Number: J59.927A
• Mol file: 2186-25-6.mol

Synonyms:2186-25-6;2-[(3-methylphenoxy)methyl]oxirane;1,2-Epoxy-3-(3-methylphenoxypropane);((m-Tolyloxy)methyl)oxirane;2-((3-Methylphenoxy)methyl)oxirane;NSC86974;TOEP;m-Tolylglycidyl ether;m-cresylglycidyl ether;glycidyl 3-methylphenylether;NCIOpen2_001159;3-methylphenyl glycidyl ether;SCHEMBL2503879;DTXSID40862861;3-(m-tolyloxy)-1,2-epoxypropane;EINECS 218-575-3;MFCD00046990;NSC 86974;NSC-86974;2,3-epoxypropyl 3-methylphenyl ether;AKOS000295046;AKOS016051082;BS-53221;FT-0756057;EN300-09421;E83881;Z56346887;F1995-0401

Chemical Property of ((m-Tolyloxy)methyl)oxirane

Chemical Property:

• Vapor Pressure: 0.0196mmHg at 25°C
• Boiling Point: 260.6°C at 760 mmHg
• Flash Point: 106°C
• PSA: 21.76000
• Density: 1.094g/cm³
• LogP: 1.77260
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 164.083729621
• Heavy Atom Count: 12
• Complexity: 147

Purity/Quality:

97% ^*data from raw suppliers

2-(3-methylphenoxymethyl)oxirane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Plastics & Rubber -> Glycidyl Ethers
• Canonical SMILES: CC1=CC(=CC=C1)OCC2CO2

Technology Process of ((m-Tolyloxy)methyl)oxirane

There total 8 articles about ((m-Tolyloxy)methyl)oxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3-methyl-phenol (108-39-4) + 1,2-Epoxy-3-bromopropane (3132-64-7,82584-73-4) → m-tolyl glycidyl ether (2186-25-6)

Guidance literature:

With potassium carbonate; In butanone; at 70 - 86 ℃; for 66h;

Reference yield: 99.0%

3-methyl-phenol (108-39-4) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → m-tolyl glycidyl ether (2186-25-6)

Guidance literature:

With potassium hydroxide; In dimethyl sulfoxide; at 20 ℃; for 3h;

DOI:10.1021/jm800227h

Reference yield: 98.72%

→ m-tolyl glycidyl ether (2186-25-6)

Guidance literature:

With caesium carbonate; In acetonitrile; at 82 ℃; for 3h;

upstream raw materials:

1,3-Dichloro-2-propanol

3-methyl-phenol

epichlorohydrin

3-amino-1,2-epoxypropane

Downstream raw materials:

1-pyrrolidino-3-m-tolyloxy-propan-2-ol

F₁₄₃₈-0002

O-[3-(3-methylphenoxy)-2-hydroxypropyl]-hydroxylamine

N-[2-(2-Hydroxy-3-m-tolyloxy-propylamino)-propyl]-2-phenyl-acetamide