6-Hepten-2-one, 1-diazo-7-phenyl-, (6E)-

Base Information

Chemical Name:6-Hepten-2-one, 1-diazo-7-phenyl-, (6E)-
CAS No.:575451-15-9
Molecular Formula:C13H14N2O
Molecular Weight:214.267
Hs Code.:

Synonyms:

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Chemical Property of 6-Hepten-2-one, 1-diazo-7-phenyl-, (6E)-

Chemical Property:

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Technology Process of 6-Hepten-2-one, 1-diazo-7-phenyl-, (6E)-

There total 10 articles about 6-Hepten-2-one, 1-diazo-7-phenyl-, (6E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 131373-87-0
(E)-6-phenylhex-5-enoyl chloride

: 18107-18-1
diazomethyl-trimethyl-silane

: 575451-15-9
(6E)-1-diazo-7-phenyl-6-hepten-2-one

Guidance literature:: (E)-6-phenylhex-5-enoyl chloride; diazomethyl-trimethyl-silane; In tetrahydrofuran; diethyl ether; acetonitrile; at 20 ℃; for 0.416667h; under 5171.62 Torr;

With polymer-supported fluoride; In tetrahydrofuran; diethyl ether; acetonitrile; at 20 ℃; under 5171.62 Torr;
DOI:10.1021/ol1027927

Reference yield:

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 575451-15-9
(6E)-1-diazo-7-phenyl-6-hepten-2-one

Guidance literature:: Multi-step reaction with 3 steps

1.1: Grubbs catalyst first generation / dichloromethane / 36 h / 20 °C / Inert atmosphere

2.1: oxalyl dichloride / dichloromethane / 5 h / 20 °C / Inert atmosphere

3.1: tetrahydrofuran; diethyl ether; acetonitrile / 0.42 h / 20 °C / 5171.62 Torr

3.2: polymer-supported fluoride / 20 °C / 5171.62 Torr

With Grubbs catalyst first generation; oxalyl dichloride; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1021/ol1027927

Reference yield:

: 16424-56-9
trans 6-phenyl-5-hexenoic acid

: 575451-15-9
(6E)-1-diazo-7-phenyl-6-hepten-2-one

Guidance literature:: Multi-step reaction with 2 steps

1.1: oxalyl dichloride / dichloromethane / 5 h / 20 °C / Inert atmosphere

2.1: tetrahydrofuran; diethyl ether; acetonitrile / 0.42 h / 20 °C / 5171.62 Torr

2.2: polymer-supported fluoride / 20 °C / 5171.62 Torr

With oxalyl dichloride; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1021/ol1027927