2,3-Hexadienoic acid, 4-phenyl-, methyl ester

Base Information

Chemical Name:2,3-Hexadienoic acid, 4-phenyl-, methyl ester
CAS No.:57585-10-1
Molecular Formula:C13H14O2
Molecular Weight:202.253
Hs Code.:

Synonyms:

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Chemical Property of 2,3-Hexadienoic acid, 4-phenyl-, methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of 2,3-Hexadienoic acid, 4-phenyl-, methyl ester

There total 11 articles about 2,3-Hexadienoic acid, 4-phenyl-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 36854-57-6
2-Phenylbutyryl chloride

: 88738-78-7
bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate

: 57585-10-1
4-phenyl-2,3-hexadienoic acid methyl ester

Guidance literature:: bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate; With isopropylmagnesium bromide; In tetrahydrofuran; at 0 ℃; for 1h; Inert atmosphere;

2-Phenylbutyryl chloride; With triethylamine; In tetrahydrofuran; at 0 ℃; for 1h; Inert atmosphere;
DOI:10.1055/s-0034-1378803

Reference yield: 44.0%

: 88738-78-7
bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate

: 351874-81-2
α-ethylbenzeneacetic acid phenyl ester

: 57585-10-1
4-phenyl-2,3-hexadienoic acid methyl ester

Guidance literature:: With 2,2,6,6-tetramethylpiperidinyl-lithium; zinc(II) chloride; In tetrahydrofuran; at -78 - 20 ℃; for 15h;
DOI:10.1016/S0957-4166(01)00114-8

Reference yield:

: 55442-34-7,55515-98-5,55515-99-6
3,3'-dimethyl-1,1'-binaphthalene-2,2'-diol

: 57585-10-1
4-phenyl-2,3-hexadienoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 72 percent / Et₃N / CH₂Cl₂ / 3 h / from 0 degC to r.t.

2: n-BuLi, KHMDS, ZnCl₂ / tetrahydrofuran / 4 h / -78 °C / effect of the base, the phosphorus compound, the ZnCl₂ amount

With n-butyllithium; potassium hexamethylsilazane; triethylamine; zinc(II) chloride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0040-4039(96)00672-7