3-Decanol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (3R)-

Base Information

Chemical Name:3-Decanol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (3R)-
CAS No.:581782-27-6
Molecular Formula:C26H40O2Si
Molecular Weight:412.688
Hs Code.:

Synonyms:

Suppliers and Price of 3-Decanol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (3R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-Decanol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (3R)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-Decanol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (3R)-

There total 1 articles about 3-Decanol, 1-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (3R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 128387-27-9
(R)-decane-1,3-diol

: 581782-27-6
C₂₆H₄₀O₂Si

Guidance literature:: With dmap; N-ethyl-N,N-diisopropylamine; In dichloromethane;
DOI:10.1016/j.bmcl.2005.08.080

Reference yield: 79.0%

: 581782-27-6
C₂₆H₄₀O₂Si

: 62-23-7
4-nitro-benzoic acid

: 851303-93-0
C₃₃H₄₃NO₅Si

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 0 ℃;
DOI:10.1016/j.bmcl.2005.08.080

Reference yield:

: 581782-27-6
C₂₆H₄₀O₂Si

: 851302-81-3
ER₈₀₉₂₆₆

Guidance literature:: Multi-step reaction with 15 steps

1.1: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / -20 - 0 °C

2.1: potassium carbonate / tetrahydrofuran; methanol / 4 h / 20 °C

3.1: dmap; triethylamine / dichloromethane / 0 - 20 °C

4.1: sodium azide / N,N-dimethyl-formamide / 140 °C

5.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1.5 h / 20 °C

6.1: dmap; triethylamine / dichloromethane / 0 - 20 °C

7.1: potassium tert-butylate / tetrahydrofuran / 1 h / 0 °C

7.2: 48 h / 0 °C

8.1: hydrogenchloride / methanol; water / 2 h / 90 °C

8.2: 20 - 90 °C

9.1: sodium hydrogencarbonate / tetrahydrofuran; water / 0.33 h / 0 °C

10.1: pyridinium trifluroacetate / dichloromethane / 2 h / -20 °C

10.2: -20 - 20 °C

11.1: triphenylphosphine / tetrahydrofuran; water / 20 °C

12.1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 20 °C

13.1: triethylsilane; trifluoroacetic acid / dichloromethane / 20 °C

14.1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine / dichloromethane / -5 - 20 °C

15.1: phenylsilane; triphenylphosphine / tetrakis(triphenylphosphine) palladium⁽⁰⁾ / tetrahydrofuran / 1 h / 20 °C

With hydrogenchloride; triethylsilane; dmap; sodium azide; phenylsilane; potassium tert-butylate; tetrabutyl ammonium fluoride; pyridinium trifluroacetate; sodium hydrogencarbonate; potassium carbonate; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; triphenylphosphine; trifluoroacetic acid; diethylazodicarboxylate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide;