Silanediamine, N,N'-bis[2,6-bis(1-methylethyl)phenyl]-1,1-diphenyl-

Base Information

• Chemical Name: Silanediamine, N,N'-bis[2,6-bis(1-methylethyl)phenyl]-1,1-diphenyl-
• CAS No.: 587023-11-8
• Molecular Formula: C36H46N2Si
• Molecular Weight: 534.86
• Mol file: 587023-11-8.mol

Synonyms:

Chemical Property of Silanediamine, N,N'-bis[2,6-bis(1-methylethyl)phenyl]-1,1-diphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silanediamine, N,N'-bis[2,6-bis(1-methylethyl)phenyl]-1,1-diphenyl-

There total 3 articles about Silanediamine, N,N'-bis[2,6-bis(1-methylethyl)phenyl]-1,1-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2,6-diisopropylbenzenamine (24544-04-5) + diphenylsilyl dichloride (80-10-4) → C37H46N2 (587023-11-8)

Guidance literature:

2,6-diisopropylbenzenamine; With n-butyllithium; In diethyl ether; hexane; at -78 - 20 ℃; Inert atmosphere;

diphenylsilyl dichloride; In diethyl ether; hexane; at -78 ℃; Inert atmosphere;

DOI:10.1002/anie.201103275

Reference yield:

[Na(THF)6]+[{Ph2Si(N(2,6-iPr2-C6H3))2}Mg(butyl)(THF)]- + 2,6-diisopropylbenzenamine (24544-04-5) → C36H54MgN3(1-)*C24H48NaO6(1+) (1571104-49-8) + C37H46N2 (587023-11-8)

Guidance literature:

In hexane; at 20 ℃; for 1h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3dt52639a

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) + diphenylsilane (775-12-2) → N-(2,6-diisopropylphenyl)-1,1-diphenylsilanamine (1414859-89-4) + C37H46N2 (587023-11-8)

Guidance literature:

In benzene-d6; at 24.84 ℃; for 12h; Glovebox; Schlenk technique; Sealed tube; Inert atmosphere;

DOI:10.1002/chem.201504316

upstream raw materials:

2,6-diisopropylbenzenamine

diphenylsilyl dichloride

diphenylsilane

Downstream raw materials:

((CH₃)2CH)2C₆H₃NSi(C₆H₅)2N((CH₃)2CH)2C₆H₃Sn

YbI(THF)2(Ph₂Si(N(2,6-iPr₂C₆H₃))2)

C₄₄H₆₀MgN₂O₂Si

Refernces

• 1、 -. "Low-cost condition iron compound synthesis". Paragraph 0026-0030. . Retrieved 2017/09/01.
• 2、 Armstrong, David R.,Clegg, William,Hernan-Gomez, Alberto,Kennedy, Alan R.,Livingstone, Zoe,Robertson, Stuart D.,Russo, Luca,Hevia, Eva. "Probing the metallating ability of a polybasic sodium alkylmagnesiate supported by a bulky bis(amido) ligand: Deprotomagnesiation reactions of nitrogen-based aromatic substrates". supporting information. p. 4361 - 4369. Retrieved 2014/03/21.