1-Phosphoryloxy-2,4-dihydroxycyclohexane

Base Information

Chemical Name:1-Phosphoryloxy-2,4-dihydroxycyclohexane
CAS No.:129832-35-5
Molecular Formula:C6H13 O6 P
Molecular Weight:212.139
Hs Code.:
DSSTox Substance ID:DTXSID60926510
Mol file:129832-35-5.mol

Synonyms:1-phosphoryloxy-2,4-dihydroxycyclohexane;1-PODCH

Suppliers and Price of 1-Phosphoryloxy-2,4-dihydroxycyclohexane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 1-Phosphoryloxy-2,4-dihydroxycyclohexane

Chemical Property:

Boiling Point:466.2±55.0 °C(Predicted)
PKA:1.91±0.10(Predicted)
PSA：101.97000
Density:1.58±0.1 g/cm3(Predicted)
LogP:0.20700
XLogP3:-0.8
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:4
Exact Mass:212.04497513
Heavy Atom Count:13
Complexity:145

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC(C(CC1O)O)OPOOO
Isomeric SMILES:C1C[C@@H]([C@@H](C[C@H]1O)O)OPOOO

Technology Process of 1-Phosphoryloxy-2,4-dihydroxycyclohexane

There total 21 articles about 1-Phosphoryloxy-2,4-dihydroxycyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2461-22-5,50727-97-4,97949-66-1,127379-34-4,127379-35-5
(1SR,3SR,6RS)-7-oxabicyclo[4.1.0]heptan-3-ol

: 129801-85-0,129801-90-7,129832-35-5,129832-36-6
Phosphoric acid mono-((1S,2R,4S)-2,4-dihydroxy-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 5 steps

1: NaH

2: Al₂O₃ / toluene / Heating

3: (COCl)2, DMSO

4: L-selectride

5: H₂ / Pd/C

With aluminum oxide; oxalyl dichloride; hydrogen; L-Selectride; sodium hydride; dimethyl sulfoxide; palladium on activated charcoal; In toluene;
DOI:10.1039/c39900000462

Reference yield:

: 2461-22-5,50727-97-4,97949-66-1,127379-34-4,127379-35-5
(1SR,3SR,6RS)-7-oxabicyclo[4.1.0]heptan-3-ol

: 129832-35-5
(1S)-phosphoryloxy-(2R,4S)-dihydroxycyclohexane

Guidance literature:: Multi-step reaction with 6 steps

1: NaH

2: Al₂O₃ / toluene / Heating

3: (COCl)2, DMSO

4: L-selectride

6: H₂ / Pd/C

With aluminum oxide; oxalyl dichloride; hydrogen; L-Selectride; sodium hydride; dimethyl sulfoxide; palladium on activated charcoal; In toluene;
DOI:10.1039/c39900000462

Reference yield:

: 822-66-2,72137-22-5
3-cyclohexen-1-ol

: 129832-35-5
(1S)-phosphoryloxy-(2R,4S)-dihydroxycyclohexane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) VO(acac)2, ButOOH, 2.) NaH, 3.) BnOH, Al₂O₃

2: 2.) L-selectride

4: H₂ / Pd/C

With aluminum oxide; bis(acetylacetonate)oxovanadium; 1-butyl hydroperoxide; hydrogen; L-Selectride; sodium hydride; benzyl alcohol; palladium on activated charcoal;
DOI:10.1080/10426509608545159