Ammiol

Base Information

Chemical Name:Ammiol
CAS No.:668-10-0
Molecular Formula:C14H12O6
Molecular Weight:276.246
Hs Code.:
UNII:6R2E7CX8FG
DSSTox Substance ID:DTXSID10216918
Nikkaji Number:J109.680J
Wikipedia:Ammiol
Wikidata:Q4747251
Mol file:668-10-0.mol

Synonyms:Ammiol;6R2E7CX8FG;UNII-6R2E7CX8FG;668-10-0;5H-Furo(3,2-g)(1)benzopyran-5-one, 7-(hydroxymethyl)-4,9-dimethoxy-;DTXSID10216918;7-(Hydroxymethyl)-4,9-dimethoxy-5H-furo(3,2-g)(1)benzopyran-5-one;C14H12O6;5H-Furo[3,2-g][1]benzopyran-5-one, 7-(hydroxymethyl)-4,9-dimethoxy-;SCHEMBL10885786;DTXCID40139409;Q4747251;7-(Hydroxymethyl)-4,9-dimethoxy-5H-furo[3,2-g]chromen-5-one #

Suppliers and Price of Ammiol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Ammiol

Chemical Property:

Vapor Pressure:5.77E-11mmHg at 25°C
Boiling Point:503.7°C at 760 mmHg
Flash Point:258.4°C
PSA：82.04000
Density:1.391g/cm³
LogP:2.04870
XLogP3:1
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:3
Exact Mass:276.06338810
Heavy Atom Count:20
Complexity:420

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=C2C(=O)C=C(OC2=C(C3=C1C=CO3)OC)CO

Technology Process of Ammiol

There total 8 articles about Ammiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 93454-52-5
khellin-2-carboxaldehyde

: 668-10-0
Ammiol

Guidance literature:: With aluminum isopropoxide; In isopropyl alcohol; for 0.25h; Heating;
DOI:10.1021/jo00200a002

Reference yield: 27.0%

: 93454-53-6
4,9-Dimethoxy-7-(iodomethyl)-5H-furo<3,2-g><1>benzopyran-5-one

: 668-10-0
Ammiol

Guidance literature:: With KO₂; In dimethyl sulfoxide; for 0.5h; Ambient temperature;
DOI:10.1021/jo00200a002

Reference yield:

: 484-51-5
5-acetyl-6-hydroxy-4,7-dimethoxybenzofuran

: 668-10-0
Ammiol

Guidance literature:: Multi-step reaction with 3 steps

1: 1) NaOMe; 2) HCl gas / 1) toluene, reflux, 15h 2) 1 min (comparable yield with NaH instead of NaOMe)

2: 79 percent / CH₃I / CH₂Cl₂ / 72 h / Heating

3: 27 percent / KO₂ / dimethylsulfoxide / 0.5 h / Ambient temperature

With hydrogenchloride; sodium methylate; methyl iodide; In dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jo00200a002