Octadecanal, 2-(methoxymethoxy)-

Base Information

• Chemical Name: Octadecanal, 2-(methoxymethoxy)-
• CAS No.: 601488-19-1
• Molecular Formula: C20H40O3
• Mol file: 601488-19-1.mol

Synonyms:

Chemical Property of Octadecanal, 2-(methoxymethoxy)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Octadecanal, 2-(methoxymethoxy)-

There total 4 articles about Octadecanal, 2-(methoxymethoxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

3-(methoxymethoxy)nonadecane-1,2-diol (601488-18-0) → 2-(methoxymethoxy)octadecanal (601488-19-1)

Guidance literature:

With lead(IV) acetate; In benzene; at 20 ℃; for 0.0833333h;

DOI:10.1002/ejoc.200300045

Reference yield:

nonadec-1-ene-3-ol (57994-84-0) → 2-(methoxymethoxy)octadecanal (601488-19-1)

Guidance literature:

Multi-step reaction with 3 steps

1: 69 percent / EtN(iPr)2 / CH₂Cl₂ / 24 h / 20 °C

2: 93 percent / OsO₄; NMO / acetone; H₂O; 2-methyl-propan-2-ol / 18 h / 20 °C

3: 95 percent / Pb(OAc)4 / benzene / 0.08 h / 20 °C

With lead(IV) acetate; osmium(VIII) oxide; N-methyl-2-indolinone; N-ethyl-N,N-diisopropylamine; In dichloromethane; water; acetone; tert-butyl alcohol; benzene;

DOI:10.1002/ejoc.200300045

Reference yield:

hexadecylmagnesium bromide (872-26-4) → 2-(methoxymethoxy)octadecanal (601488-19-1)

Guidance literature:

Multi-step reaction with 4 steps

1: 52 percent / diethyl ether / 1 h / 0 °C

2: 69 percent / EtN(iPr)2 / CH₂Cl₂ / 24 h / 20 °C

3: 93 percent / OsO₄; NMO / acetone; H₂O; 2-methyl-propan-2-ol / 18 h / 20 °C

4: 95 percent / Pb(OAc)4 / benzene / 0.08 h / 20 °C

With lead(IV) acetate; osmium(VIII) oxide; N-methyl-2-indolinone; N-ethyl-N,N-diisopropylamine; In diethyl ether; dichloromethane; water; acetone; tert-butyl alcohol; benzene;

DOI:10.1002/ejoc.200300045

upstream raw materials:

3-(methoxymethoxy)nonadecane-1,2-diol

nonadec-1-ene-3-ol

hexadecylmagnesium bromide

3-(methoxymethoxy)nonadec-1-ene

Refernces