1,5,6-Heptanetriol, 6-methyl-3-[3-methyl-4-(phenylmethoxy)phenyl]-, 1-acetate, (3S)-

Base Information

Chemical Name:1,5,6-Heptanetriol, 6-methyl-3-[3-methyl-4-(phenylmethoxy)phenyl]-, 1-acetate, (3S)-
CAS No.:603095-53-0
Molecular Formula:C₂₄H₃₂O₅
Molecular Weight:400.515
Hs Code.:

Synonyms:

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Chemical Property of 1,5,6-Heptanetriol, 6-methyl-3-[3-methyl-4-(phenylmethoxy)phenyl]-, 1-acetate, (3S)-

Chemical Property:

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Technology Process of 1,5,6-Heptanetriol, 6-methyl-3-[3-methyl-4-(phenylmethoxy)phenyl]-, 1-acetate, (3S)-

There total 16 articles about 1,5,6-Heptanetriol, 6-methyl-3-[3-methyl-4-(phenylmethoxy)phenyl]-, 1-acetate, (3S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 603095-32-5
Acetic acid (R)-3-(4-benzyloxy-3-methyl-phenyl)-6-methyl-hept-5-enyl ester

: 603095-53-0
Acetic acid (S)-3-(4-benzyloxy-3-methyl-phenyl)-5,6-dihydroxy-6-methyl-heptyl ester

Guidance literature:: With AD-mix-β;
DOI:10.1016/S0040-4039(03)01094-3

Reference yield:

: 532423-91-9
3-(4-benzyloxy-3-methyl-phenyl)-pentanedioic acid dimethyl ester

: 603095-53-0
Acetic acid (S)-3-(4-benzyloxy-3-methyl-phenyl)-5,6-dihydroxy-6-methyl-heptyl ester

Guidance literature:: Multi-step reaction with 16 steps

1: PLE / dimethylsulfoxide

2: BOP; Et₃N

3: LiBH₄ / diethyl ether; ethanol

4: CSA / benzene

5: DIBAL-H / benzene

6: BF₃*OEt₂

7: 99 percent / imidazole / dimethylformamide

8: MeI; NaHCO₃ / acetonitrile; H₂O

9: NaBH₄ / ethanol

10: 86 percent / pyridine

11: 98 percent / TBAF / tetrahydrofuran

12: SO₃*pyr; DMSO; Et₃N / CH₂Cl₂

13: K₂CO₃; MeOH

14: 91 percent / nBuLi / tetrahydrofuran

15: 96 percent / pyridine

16: 100 percent / AD-mix-β

With pyridine; 1H-imidazole; methanol; sodium tetrahydroborate; lithium borohydride; n-butyllithium; pyridine-SO₃ complex; AD-mix-β; camphor-10-sulfonic acid; boron trifluoride diethyl etherate; tetrabutyl ammonium fluoride; diisobutylaluminium hydride; sodium hydrogencarbonate; potassium carbonate; (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate; dimethyl sulfoxide; triethylamine; methyl iodide; In tetrahydrofuran; diethyl ether; ethanol; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; acetonitrile; benzene; 14: Wittig reaction / 16: Sharpless asymmetric dihydroxylation;
DOI:10.1016/S0040-4039(03)01094-3

Reference yield:

: (S)-3-(4-Benzyloxy-3-methyl-phenyl)-5-hydroxy-pentanal

: 603095-53-0
Acetic acid (S)-3-(4-benzyloxy-3-methyl-phenyl)-5,6-dihydroxy-6-methyl-heptyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / nBuLi / tetrahydrofuran

2: 96 percent / pyridine

3: 100 percent / AD-mix-β

With pyridine; n-butyllithium; AD-mix-β; In tetrahydrofuran; 1: Wittig reaction / 3: Sharpless asymmetric dihydroxylation;
DOI:10.1016/S0040-4039(03)01094-3