(methylsulfonimidoyl)benzene

Base Information

• Chemical Name: (methylsulfonimidoyl)benzene
• CAS No.: 4381-25-3
• Molecular Formula: C7H9 N O S
• Molecular Weight: 155.221
• Hs Code.: 2925290090
• Mol file: 4381-25-3.mol

Synonyms:Methylphenyl sulfoximine; NSC 152380; NSC 152588; S-Methyl-S-phenylsulfoxime;S-Methyl-S-phenylsulfoximide; S-Methyl-S-phenylsulfoximine;rac-S-Methyl-S-phenylsulfoximine

Chemical Property of (methylsulfonimidoyl)benzene

Chemical Property:

• Melting Point: 34-36 °C
• Boiling Point: 237.8°Cat760mmHg
• Flash Point: 97.6°C
• PSA: 49.30000
• Density: 1.14g/cm³
• LogP: 2.68750

Purity/Quality:

99% ^*data from raw suppliers

(Methylsulfonimidoyl)benzene 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (methylsulfonimidoyl)benzene

There total 89 articles about (methylsulfonimidoyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

methyl-phenyl-thioether (100-68-5) → S-methyl-S-phenylsulfoximine (4381-25-3)

Guidance literature:

With diacetoxyiodo-3,4,5-trifluorobenzene; water; ammonium carbonate; at 25 ℃; for 16h; Reagent/catalyst; Green chemistry;

DOI:10.1002/cssc.201903430

Reference yield: 99.0%

S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfoximide (42153-74-2) → S-methyl-S-phenylsulfoximine (4381-25-3)

Guidance literature:

With sulfuric acid; at 120 ℃; for 0.416667h; Inert atmosphere;

DOI:10.1039/c0cc00976h

Reference yield: 97.0%

C9H10Cl3NO4S2 → S-methyl-S-phenylsulfoximine (4381-25-3)

Guidance literature:

C₉H₁₀Cl₃NO₄S₂; With acetic acid; zinc; at 25 ℃; for 12h;

With acetyl chloride; In methanol; at 25 ℃; for 1h;

DOI:10.1021/acscatal.5b02495

upstream raw materials:

tert-butylethylene

N-chloro-S-methyl-S-phenyl sulfoximine

racemic methyl phenyl sulfoxide

Phenyl-methyl-sulfilimin

Downstream raw materials:

(-)-(R)-Methylphenyloxosulfonium-bis-(methoxycarbonyl)-methylid

(N-Benzyl)-methylphenylsulfoximid

methyl phenyl sulfonium bismethoxycarbonylmethylide

N-methoxycarbonyl-S-methyl-S-phenylsulfoximines

Refernces

• 1、 Cho, Gae Young,Bolm, Carsten. "Metal-free imination of sulfoxides and sulfides". . p. 8007 - 8008. Retrieved 2005.
• 2、 Alharbi, Haifa,Elsherbini, Mohamed,Karam, Fatemah,Osi, Arnaud,Wirth, Thomas. "Sulfur-Based Chiral Iodoarenes: An Underexplored Class of Chiral Hypervalent Iodine Reagents". . . Retrieved 2021/06/21.
• 3、 Hermann, Mathias,Wassy, Daniel,Kohn, Julia,Seitz, Philipp,Betschart, Martin U.,Grimme, Stefan,Esser, Birgit. "Chiral Dibenzopentalene-Based Conjugated Nanohoops through Stereoselective Synthesis". supporting information. p. 10680 - 10689. Retrieved 2021/04/02.