alpha-Rotunol

Base Information

Chemical Name:alpha-Rotunol
CAS No.:24405-56-9
Molecular Formula:C₁₅H₂₂O₂
Molecular Weight:234.338
Hs Code.:
Wikidata:Q104400796
Mol file:24405-56-9.mol

Synonyms:beta-Rotunol;alpha-Rotunol;24405-57-0;a-Rotunol;(4aR,6R,8aS)-4a-hydroxy-4,8a-dimethyl-6-prop-1-en-2-yl-5,6,7,8-tetrahydro-1H-naphthalen-2-one;[4aS-(4aalpha,6beta,8abeta)]-4a,5,6,7,8,8a-hexahydro-4a-hydroxy-4,8a-dimethyl-6-(1-methylethenyl)-2(1H)-naphthalenone

Suppliers and Price of alpha-Rotunol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of alpha-Rotunol

Chemical Property:

PSA：37.30000
LogP:3.01910
XLogP3:2.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:234.161979940
Heavy Atom Count:17
Complexity:407

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=O)CC2(C1(CC(CC2)C(=C)C)O)C

Technology Process of alpha-Rotunol

There total 4 articles about alpha-Rotunol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 82509-18-0
(1S,3R,6S,8R)-3-Isopropenyl-6,11-dimethyl-9,10-dioxa-tricyclo[6.2.2.0^1,6]dodec-11-ene

: 24405-56-9
α-rotunol

Guidance literature:: With aluminum oxide; In diethyl ether; for 16h; Yield given; Ambient temperature;
DOI:10.1246/bcsj.55.1195

Reference yield:

: 473-08-5
eudesma-4,11-dien-3-one

: 24405-56-9
α-rotunol

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) tosylhydrazine, conc. HCl, 2.) methyllithium / 1.) THF, reflux, 7 h, 2.) benzene, ether, RT, 30 min

2: 64 mg / tungsten(VI) chloride / CH₂Cl₂ / 2 h / -78 °C

3: alumina / diethyl ether / 16 h / Ambient temperature

With hydrogenchloride; aluminum oxide; methyllithium; tungsten(VI) chloride; toluene-4-sulfonic acid hydrazide; In diethyl ether; dichloromethane;
DOI:10.1246/bcsj.55.1195

Reference yield:

: 82462-31-5
(-)-eudesma-3,4,11-triene

: 24405-56-9
α-rotunol

Guidance literature:: Multi-step reaction with 2 steps

1: 64 mg / tungsten(VI) chloride / CH₂Cl₂ / 2 h / -78 °C

2: alumina / diethyl ether / 16 h / Ambient temperature

With aluminum oxide; tungsten(VI) chloride; In diethyl ether; dichloromethane;
DOI:10.1246/bcsj.55.1195