Benzene, 1,1'-(1,2-ethenediyl)bis[4-(bromomethyl)-

Base Information

• Chemical Name: Benzene, 1,1'-(1,2-ethenediyl)bis[4-(bromomethyl)-
• CAS No.: 60682-97-5
• Molecular Formula: C₁₆H₁₄Br₂
• Molecular Weight: 366.095
• DSSTox Substance ID: DTXSID80408949
• Mol file: 60682-97-5.mol

Synonyms:Benzene, 1,1'-(1,2-ethenediyl)bis[4-(bromomethyl)-;60682-97-5;DTXSID80408949

Chemical Property of Benzene, 1,1'-(1,2-ethenediyl)bis[4-(bromomethyl)-

Chemical Property:

• XLogP3: 5.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 365.94418
• Heavy Atom Count: 18
• Complexity: 220

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1CBr)C=CC2=CC=C(C=C2)CBr

Technology Process of Benzene, 1,1'-(1,2-ethenediyl)bis[4-(bromomethyl)-

There total 15 articles about Benzene, 1,1'-(1,2-ethenediyl)bis[4-(bromomethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

1-(bromomethyl)-4-vinylbenzene (13368-25-7) + 1-bromomethyl-4-bromobenzene (589-15-1) → (1E)-1,2-bis[3-(bromomethyl)phenyl]diazene (60682-97-5,66888-72-0,29477-66-5)

Guidance literature:

With potassium carbonate; In water; N,N-dimethyl-formamide; at 70 ℃; for 3h; Inert atmosphere;

DOI:10.1007/s11164-018-3265-8

Reference yield: 74.0%

4,4'-bis(hydroxymethyl)-trans-stilbene (66888-68-4) → (1E)-1,2-bis[3-(bromomethyl)phenyl]diazene (60682-97-5,66888-72-0,29477-66-5)

Guidance literature:

With N-Bromosuccinimide; triphenylphosphine; In tetrahydrofuran;

DOI:10.1021/jo900443e

Reference yield: 60.0%

(E)-4,4'-dimethylstilbene (18869-29-9) → (1E)-1,2-bis[3-(bromomethyl)phenyl]diazene (60682-97-5,66888-72-0,29477-66-5)

Guidance literature:

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); In tetrachloromethane; for 6h; Reflux;

DOI:10.1039/c4ra10952j

upstream raw materials:

(E)-4,4'-dimethylstilbene

4,4'-bis(hydroxymethyl)-trans-stilbene

4-methyl-benzaldehyde

trans-4,4'-dimethyl 4,4'-dicarboxylate-1,2-diphenylethylene

Downstream raw materials:

trans-Stilben-4,4'-bis(methylamin)-N,N,N',N'-tetraessigsaeure-tetramethylester

(1Z)-1,2-bis[3-(bromomethyl)phenyl]diazene

(E)-4,4'-bis(diethylphosphonatemethyl)stilbene

4,4'-bis(mercaptomethyl)-trans-stilbene