Perplanone D

Base Information

Chemical Name:Perplanone D
CAS No.:123163-72-4
Molecular Formula:C₁₅H₂₀O
Molecular Weight:216.323
Hs Code.:

Synonyms:perplanone D

Suppliers and Price of Perplanone D

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Perplanone D

Chemical Property:

Vapor Pressure:0.000177mmHg at 25°C
Boiling Point:329.5°Cat760mmHg
Flash Point:146.9°C
PSA：17.07000
Density:0.93g/cm³
LogP:3.84630
XLogP3:4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:216.151415257
Heavy Atom Count:16
Complexity:356

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)C1CC(=O)C(=C)C=CCC(=C)C=C1
Isomeric SMILES:CC(C)[C@@H]/1CC(=O)C(=C)/C=C\CC(=C)/C=C1

Technology Process of Perplanone D

There total 23 articles about Perplanone D which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: (3Z,7E)-(S)-9-Isopropyl-2,6-dimethylene-cyclodeca-3,7-dienol

: 123163-72-4
(-)-periplanone C

Guidance literature:: With Dess-Martin periodane;
DOI:10.1016/S0040-4039(00)60712-8

Reference yield: 60.1%

: 191287-32-8
(3Z,7E)-(1S,9S)-9-Isopropyl-2,6-dimethylene-cyclodeca-3,7-dienol

: 123163-72-4
(-)-periplanone C

Guidance literature:: With N-methyl-2-indolinone; tetrapropylammonium perruthennate; In dichloromethane; at 20 ℃; for 0.416667h;
DOI:10.1271/bbb.64.600

Reference yield:

: 5989-54-8,555-08-8,8022-90-0,9003-73-0,95327-98-3
(-)-(S)-limonene

: 123163-72-4
(-)-periplanone C

Guidance literature:: Multi-step reaction with 17 steps

1: H₂, Wilkinson catalyst

2: O₃ / ethanol / -78 °C

3: NaBH₄ / tetrahydrofuran; ethanol

4: imidazole / dimethylformamide

5: Br₂ / CCl₄

6: 67 percent / Li₂CO₃, LiBr / dimethylformamide

7: tetrahydrofuran

8: LiN(iPr)2 / tetrahydrofuran

9: LiCl, methanesulfonyl chloride / dimethylformamide

10: K₂CO₃, CuI, Bu₄NBr / dimethylformamide

11: 90 percent / H₂ / Lindlar catalyst

12: 83 percent / Bu₄NF, H₂O / tetrahydrofuran

13: Dess-Martin periodinane, NaOAc / CH₂Cl₂

14: TiCl₃*DME_1.5, Zn-Cu / 1,2-dimethoxy-ethane / 36 h / 0 °C

15: 1.) MsCl, pyridine 2.) Bu₄NOH / 1.) ether; 2.) THF

16: LiN(iPr)2 / tetrahydrofuran

17: 84 percent / Dess-Martin periodinane

With pyridine; 1H-imidazole; sodium tetrahydroborate; copper(l) iodide; Wilkinson's catalyst; TiCl₃-1,2-dimethoxyethane; tetrabutyl ammonium fluoride; tetrabutylammomium bromide; tetra(n-butyl)ammonium hydroxide; water; hydrogen; bromine; sodium acetate; lithium carbonate; copper; potassium carbonate; Dess-Martin periodane; ozone; methanesulfonyl chloride; lithium chloride; lithium bromide; zinc; lithium diisopropyl amide; Lindlar's catalyst; In tetrahydrofuran; tetrachloromethane; 1,2-dimethoxyethane; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)60712-8