1,1':4',1''-Terphenyl, 2,2',2'',3,3',3'',5,5',5'',6,6',6''-dodecafluoro-

Base Information

Chemical Name:1,1':4',1''-Terphenyl, 2,2',2'',3,3',3'',5,5',5'',6,6',6''-dodecafluoro-
CAS No.:63107-91-5
Molecular Formula:C18H2F12
Molecular Weight:446.195
Hs Code.:
DSSTox Substance ID:DTXSID90571895
Nikkaji Number:J1.017.581J
Wikidata:Q82460083

Synonyms:63107-91-5;1,1':4',1''-Terphenyl, 2,2',2'',3,3',3'',5,5',5'',6,6',6''-dodecafluoro-;2,2',2'',3,3',3'',5,5',5'',6,6',6''-Dodecafluoro-1,1':4',1''-terphenyl;DTXSID90571895;1,2,4,5-Tetrafluoro-3,6-bis(2,3,5,6-tetrafluorophenyl)benzene;1~2~,1~3~,1~5~,1~6~,2~2~,2~3~,2~5~,2~6~,3~2~,3~3~,3~5~,3~6~-Dodecafluoro-1~1~,2~1~:2~4~,3~1~-terphenyl

Suppliers and Price of 1,1':4',1''-Terphenyl, 2,2',2'',3,3',3'',5,5',5'',6,6',6''-dodecafluoro-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,1':4',1''-Terphenyl, 2,2',2'',3,3',3'',5,5',5'',6,6',6''-dodecafluoro-

Chemical Property:

XLogP3:6.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:12
Rotatable Bond Count:2
Exact Mass:445.9964880
Heavy Atom Count:30
Complexity:500

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=C(C(=C(C(=C1F)F)C2=C(C(=C(C(=C2F)F)C3=C(C(=CC(=C3F)F)F)F)F)F)F)F

Technology Process of 1,1':4',1''-Terphenyl, 2,2',2'',3,3',3'',5,5',5'',6,6',6''-dodecafluoro-

There total 1 articles about 1,1':4',1''-Terphenyl, 2,2',2'',3,3',3'',5,5',5'',6,6',6''-dodecafluoro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 392-57-4
1,4-diiodo-2,3,5,6-tetrafluorobenzene

: 3883-86-1
2,2',3,3',5,5',6,6'-octafluoro-1,1'-biphenyl

: 63107-91-5
2,2′,2″,3,3′,3″,5,5′,5″,6,6′,6″-dodecafluoro-1,1′:4′,1″-terphenyl

: 63107-92-6
2,3,5,6,2',3',5',6',2'',3'',5'',6'',2''',3''',5''',6'''-hexadecafluoro-<1,1';4',1'';4'',1'''>-quaterphenyl

: 2,3,5,6,2',3',5',6',2'',3'',5'',6'',2''',3''',5''',6''',2'''',3'''',5'''',6''''-eicosafluoro-<1,1';4',1'';4'',1''';4''',1''''>-quinquephenyl

Guidance literature:: With 1-methyl-pyrrolidin-2-one; lithium aluminium tetrahydride; copper(I) thiophene-2-carboxylate; Yields of byproduct given; 1.) NMP, room temperature, 96 h, 2.) ether, THF, 0 deg C, 1 h.;
DOI:10.1016/S0040-4020(98)00919-3

Reference yield:

: 63107-91-5
2,2′,2″,3,3′,3″,5,5′,5″,6,6′,6″-dodecafluoro-1,1′:4′,1″-terphenyl

: 5630-57-9
perfluoro-(1,1':4',1'':4'',1''':4''',1''''-quinquephenyl)

Guidance literature:: Multi-step reaction with 2 steps

1.1: 33 percent / Br₂; sulfuric acid; aluminum bromide / 72 h / 60 °C

2.1: magnesium / tetrahydrofuran / 1 h / 20 °C

2.2: copper(I) bromide / tetrahydrofuran; dioxane / 20 °C

2.3: 54 percent / tetrahydrofuran; dioxane; toluene / 96 h / 80 °C

With aluminum tri-bromide; sulfuric acid; bromine; magnesium; In tetrahydrofuran;
DOI:10.1021/ja002309o

Reference yield:

: 63107-91-5
2,2′,2″,3,3′,3″,5,5′,5″,6,6′,6″-dodecafluoro-1,1′:4′,1″-terphenyl

: perfluoro-p-septiphenyl

Guidance literature:: Multi-step reaction with 2 steps

1.1: 33 percent / Br₂; sulfuric acid; aluminum bromide / 72 h / 60 °C

2.1: magnesium / tetrahydrofuran / 1 h / 20 °C

2.2: copper(I) bromide / tetrahydrofuran; dioxane / 20 °C

2.3: 54 percent / tetrahydrofuran; dioxane; toluene / 24 h / 95 °C

With aluminum tri-bromide; sulfuric acid; bromine; magnesium; In tetrahydrofuran;
DOI:10.1021/ja002309o