1,2-diamino-4,5-ethylenedioxybenzene

Base Information

• Chemical Name: 1,2-diamino-4,5-ethylenedioxybenzene
• CAS No.: 81927-47-1
• Molecular Formula: C₈H₁₀N₂O₂
• Molecular Weight: 166.18
• Hs Code.: 2932999099
• Mol file: 81927-47-1.mol

Synonyms:1,4-benzodioxane-6,7-diamine;6,7-diamino-2,3-dihydro-1,4-benzodioxine;6,7-diamino-2,3-dihydro-1,4-benzodioxin;1,2-diamino-4,5-ethylenedioxybenzene;7-amino-2,3-dihydro-1,4-benzodioxin-6-ylamine;2,3-dihydro-1,4-benzodioxin-6,7-diamine;1,4-benzodioxin-6,7-diamine,2,3-dihydro;

Chemical Property of 1,2-diamino-4,5-ethylenedioxybenzene

Chemical Property:

• Vapor Pressure: 1.71E-05mmHg at 25°C
• Boiling Point: 364.2°Cat760mmHg
• Flash Point: 208.5°C
• PSA: 70.50000
• Density: 1.352g/cm³
• LogP: 1.78460

Purity/Quality:

97% ^*data from raw suppliers

2,3-Dihydro-1,4-benzodioxine-6,7-diamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-diamino-4,5-ethylenedioxybenzene

There total 8 articles about 1,2-diamino-4,5-ethylenedioxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

7-amino-6-ethocycarbonylamino-2,3-dihydro-1,4-benzodioxine (475112-07-3) → 7-amino-2,3-dihydro-1,4-benzodioxin-6-ylamine (81927-47-1)

Guidance literature:

With potassium hydroxide; In ethanol; for 4h; Heating;

DOI:10.1016/S0040-4020(02)00500-8

Reference yield: 72.0%

7-nitro-2,3-dihydro-1,4-benzodioxin-6-amine (62140-78-7) → 7-amino-2,3-dihydro-1,4-benzodioxin-6-ylamine (81927-47-1)

Guidance literature:

With hydrogen; palladium 10% on activated carbon; In methanol; for 18h;

Reference yield:

6,7-dinitro-2,3-dihydrobenzo[1,4]dioxine (57356-48-6) → 7-amino-2,3-dihydro-1,4-benzodioxin-6-ylamine (81927-47-1)

Guidance literature:

With hydrogen; In ethanol; under 22801.5 Torr;

DOI:10.5012/bkcs.2011.32.8.2643

upstream raw materials:

7-amino-6-ethocycarbonylamino-2,3-dihydro-1,4-benzodioxine

benzo-1,4-dioxane

6,7-dinitro-2,3-dihydrobenzo[1,4]dioxine

N-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)acetamide

Downstream raw materials:

6,7-dihydro-1H-[1,4]dioxino[2',3':4,5]benzo[d]imidazol-2-yl methanol

1-[7-(2,4-diphenylpyrrol-1-yl)-2,3-dihydro-1,4-benzodioxin-6-yl]-2,4-diphenylpyrrole

N,N'-(ethylenedioxy)benzenebis(salicylideneimine)

6,7-dihydro-1H-[1,4]dioxino[2',3':4,5]benzo[d]imidazole-2-thiol