METHYL-3-AMINO-3-DEOXY-B-D-*GLUCOPYRANOS IDE

Base Information

• Chemical Name: METHYL-3-AMINO-3-DEOXY-B-D-*GLUCOPYRANOS IDE
• CAS No.: 14133-36-9
• Molecular Formula: C7H15NO5
• Molecular Weight: 193.2
• Hs Code.: 2932999099
• Mol file: 14133-36-9.mol

Synonyms:Glucopyranoside,methyl 3-amino-3-deoxy-, b-D- (8CI);NSC 236639;Methyl 3-amino-3-deoxyhexopyranoside;

Chemical Property of METHYL-3-AMINO-3-DEOXY-B-D-*GLUCOPYRANOS IDE

Chemical Property:

• Vapor Pressure: 1.57E-08mmHg at 25°C
• Refractive Index: 1.55
• Boiling Point: 412.6 °C at 760 mmHg
• Flash Point: 203.3 °C
• PSA: 105.17000
• Density: 1.39 g/cm³
• LogP: -1.90060
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

METHYL-3-AMINO-3-DEOXY-BETA-D-GLUCOPYRANOSIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL-3-AMINO-3-DEOXY-B-D-*GLUCOPYRANOS IDE

There total 5 articles about METHYL-3-AMINO-3-DEOXY-B-D-*GLUCOPYRANOS IDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

methyl 3-nitro-β-D-3-deoxy-glucopyranoside (4631-21-4,409095-60-9) → methyl-β-kanopyranosaminide (14133-36-9,686298-97-5)

Guidance literature:

With hydrogen; In methanol; for 3h; under 26252.6 Torr;

DOI:10.1016/j.carres.2009.03.016

Reference yield:

methyl-[O2,O4,O6-triacetyl-O3-(toluene-4-sulfonyl)-β-D-glucopyranoside] (17690-23-2) → methyl-β-kanopyranosaminide (14133-36-9,686298-97-5)

Guidance literature:

With methanol; chloroform; sodium methylate; Erhitzen des Reaktionsprodukts mit Ammoniak in Methanol auf 150grad;

DOI:10.1039/jr9380001810

Reference yield:

→ methyl-(3-amino-3-deoxy-β-D-allopyranoside) (34626-97-6,686298-97-5) + methyl-β-kanopyranosaminide (14133-36-9,686298-97-5)

Guidance literature:

With hydroxylamine hydrochloride; water; Behandeln des Reaktionsprodukts mit Butan-1-ol, Aethanol und Natrium-Amalgam unter Zusatz von Essigsaeure;

upstream raw materials:

methyl-[O²,O⁴,O⁶-triacetyl-O³-(toluene-4-sulfonyl)-β-D-glucopyranoside]

methyl 3-nitro-β-D-3-deoxy-glucopyranoside

Downstream raw materials:

dibecacin

((2R,3S,4S,5R,6R)-3,5-Bis-benzyloxy-2-benzyloxymethyl-6-bromo-tetrahydro-pyran-4-yl)-(2,4-dinitro-phenyl)-amine

(3R,4S,5S,6R)-3,5-Bis-benzyloxy-6-benzyloxymethyl-4-(2,4-dinitro-phenylamino)-tetrahydro-pyran-2-ol

penta-N-acetyldibekacin

Refernces