8-Hexadecenedioic acid, dimethyl ester, (E)-

Base Information

• Chemical Name: 8-Hexadecenedioic acid, dimethyl ester, (E)-
• CAS No.: 63318-25-2
• Molecular Formula: C18H32O4
• Molecular Weight: 312.45
• Mol file: 63318-25-2.mol

Synonyms:

Chemical Property of 8-Hexadecenedioic acid, dimethyl ester, (E)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 8-Hexadecenedioic acid, dimethyl ester, (E)-

There total 2 articles about 8-Hexadecenedioic acid, dimethyl ester, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethyl hexadec-8-enedioate (57568-17-9) → methyl non-8-enoate (20731-23-1) + (E)-8-hexadecenedioc acid dimethyl ester (63318-25-2)

Guidance literature:

With ethene; [2-(1-methylethoxy-κO)phenylmethyl-κC](nitrato-κO,κO′){rel-(2R,5R,7S)-tricyclo[3.3.1.1^3,7]decane-2,1-diyl[3-(2,4,6-trimethylphenyl)-1-imidazolidinyl-2-ylidene]}ruthenium; In tetrahydrofuran; at 35 ℃; for 6h; under 3800.26 Torr; Sealed tube;

DOI:10.1021/ja4010267

Reference yield:

methyl non-8-enoate (20731-23-1) → (Z)-8-hexadecenedioc acid dimethyl ester (63318-26-3) + (E)-8-hexadecenedioc acid dimethyl ester (63318-25-2)

Guidance literature:

With Grubbs catalyst first generation; In neat (no solvent); at 35 ℃; for 16h; under 30 Torr; Overall yield = 89 %; Overall yield = 2.7 g; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1021/ja4010267

upstream raw materials:

dimethyl hexadec-8-enedioate

methyl non-8-enoate