1-Chloro-4-(ethenesulfinyl)benzene

Base Information

Chemical Name:1-Chloro-4-(ethenesulfinyl)benzene
CAS No.:63383-26-6
Molecular Formula:C8H7ClOS
Molecular Weight:186.662
Hs Code.:
DSSTox Substance ID:DTXSID90491660
Nikkaji Number:J653.282I

Synonyms:63383-26-6;1-Chloro-4-(vinylsulfinyl)benzene;1-Chloro-4-(ethenesulfinyl)benzene;p-chlorephenyl vinyl sulfoxide;SCHEMBL5835270;DTXSID90491660

Suppliers and Price of 1-Chloro-4-(ethenesulfinyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 1-Chloro-4-(ethenesulfinyl)benzene

Chemical Property:

Boiling Point:344.0±25.0 °C(Predicted)
PSA：36.28000
Density:1.33±0.1 g/cm3(Predicted)
LogP:3.45680
XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:185.9906137
Heavy Atom Count:11
Complexity:162

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CS(=O)C1=CC=C(C=C1)Cl

Technology Process of 1-Chloro-4-(ethenesulfinyl)benzene

There total 2 articles about 1-Chloro-4-(ethenesulfinyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 16411-16-8
p-chlorophenyl vinyl sulfide

: 63383-26-6
1-chloro-4-(vinylsulfinyl)benzene

Guidance literature:: With dihydrogen peroxide; acetic acid; In water; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/ol102798f

Reference yield:

: 106-54-7
p-Chlorothiophenol

: 63383-26-6
1-chloro-4-(vinylsulfinyl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium; ethanol / 0.5 h / 20 °C

1.2: Reflux

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.5 h / -78 - 20 °C

With ethanol; sodium; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1016/j.tet.2020.131633

Reference yield: 94.0%

: 625-86-5
2,5-dimethylfuran

: 63383-26-6
1-chloro-4-(vinylsulfinyl)benzene

: (1SR,2SR,4SR)-2-(4-chlorophenylsulfinyl)-1,4-dimethyl-7-oxabicyclo[2.2.1]hept-5-ene

Guidance literature:: With 2,6-di-tert-butyl-pyridine; t-butyldimethylsiyl triflate; In acetonitrile; at -30 ℃; for 36h; Inert atmosphere;
DOI:10.1021/ol102798f