4-Bromo-4'-heptyloxybiphenyl

Base Information

Chemical Name:4-Bromo-4'-heptyloxybiphenyl
CAS No.:63619-65-8
Molecular Formula:C19H23BrO
Molecular Weight:347.295
Hs Code.:
DSSTox Substance ID:DTXSID20576277
Wikidata:Q82465865

Synonyms:4-bromo-4'-heptyloxybiphenyl;63619-65-8;4'-Bromo-4-heptyloxy-biphenyl;SCHEMBL2356412;DTXSID20576277;RPKKVGYCNBDCKG-UHFFFAOYSA-N;4-BROMO-4'-(HEPTYLOXY)-1,1'-BIPHENYL

Suppliers and Price of 4-Bromo-4'-heptyloxybiphenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of 4-Bromo-4'-heptyloxybiphenyl

Chemical Property:

Boiling Point:427.9±28.0 °C(Predicted)
PSA：9.23000
Density:1.181±0.06 g/cm3(Predicted)
LogP:6.46530
XLogP3:7.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:8
Exact Mass:346.09323
Heavy Atom Count:21
Complexity:252

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCCOC1=CC=C(C=C1)C2=CC=C(C=C2)Br

Technology Process of 4-Bromo-4'-heptyloxybiphenyl

There total 1 articles about 4-Bromo-4'-heptyloxybiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.3%

: 629-04-9
1-Bromoheptane

: 29558-77-8
4-bromo-4'-hydroxybiphenyl

: 63619-65-8
4-bromo-4'-n-heptyloxybiphenyl

Guidance literature:: With potassium carbonate; In butanone; for 8h; Reflux;
DOI:10.1016/j.ejmech.2012.01.054

Reference yield: 88.0%

: 63619-65-8
4-bromo-4'-n-heptyloxybiphenyl

: 52364-72-4
4'-(heptyloxy)(1,1'-biphenyl)-4-carbonitrile

Guidance literature:: With iodophenylbis(triphenylphosphine)palladium; In N,N-dimethyl-formamide; for 2h; Heating;

Reference yield:

: 63619-65-8
4-bromo-4'-n-heptyloxybiphenyl

: C₄₁H₅₄N₄O₇

Guidance literature:: Multi-step reaction with 5 steps

1.1: n-butyllithium / tert-butyl methyl ether / 2 h / -20 °C / Inert atmosphere

1.2: -60 - 20 °C

1.3: 0.17 h / 20 °C

2.1: palladium diacetate; sodium carbonate; triphenylphosphine / propan-1-ol; toluene / 4 h / Reflux; Inert atmosphere

3.1: cetyltrimethylammonim bromide; potassium hydroxide / 5,5-dimethyl-1,3-cyclohexadiene / 3 h / Reflux

3.2: 0.5 h / pH 1 / Reflux

4.1: dmap; benzotriazol-1-ol; dicyclohexyl-carbodiimide / dichloromethane / 48 h / 20 °C

4.2: 48 h / 20 °C

5.1: trifluoroacetic acid / dichloromethane / 0.75 h / 20 °C

With dmap; n-butyllithium; cetyltrimethylammonim bromide; palladium diacetate; sodium carbonate; benzotriazol-1-ol; dicyclohexyl-carbodiimide; triphenylphosphine; trifluoroacetic acid; potassium hydroxide; In propan-1-ol; 5,5-dimethyl-1,3-cyclohexadiene; dichloromethane; tert-butyl methyl ether; toluene; 2.1: Suzuki reaction;
DOI:10.1016/j.ejmech.2012.01.054