Oxirane, 2,2-dimethyl-3-[3,7,11-trimethyl-13-(phenylthio)-3,7,11-tridecatrienyl]-, (E,E,E)-

Base Information

Chemical Name:Oxirane, 2,2-dimethyl-3-[3,7,11-trimethyl-13-(phenylthio)-3,7,11-tridecatrienyl]-, (E,E,E)-
CAS No.:63859-99-4
Molecular Formula:C26H38OS
Molecular Weight:398.653
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Oxirane, 2,2-dimethyl-3-[3,7,11-trimethyl-13-(phenylthio)-3,7,11-tridecatrienyl]-, (E,E,E)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Oxirane, 2,2-dimethyl-3-[3,7,11-trimethyl-13-(phenylthio)-3,7,11-tridecatrienyl]-, (E,E,E)-

There total 11 articles about Oxirane, 2,2-dimethyl-3-[3,7,11-trimethyl-13-(phenylthio)-3,7,11-tridecatrienyl]-, (E,E,E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

: 132274-05-6
(2S,3R)-2-Iodomethyl-2-methyl-3-((3E,7E,11E)-3,7,11-trimethyl-13-phenylsulfanyl-trideca-3,7,11-trienyl)-oxirane

: 63859-99-4
(14R,all-E)-14,15-Epoxy-3,7,11,15-tetramethyl-1-(phenylthio)hexadeca-2,6,10-trien

Guidance literature:: With sodium cyanoborohydride; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; for 24h; Ambient temperature;
DOI:10.1002/hlca.19900730721

Reference yield:

: 1117-52-8
6,10,14-trimethyl-5,9,13-pentadecatriene-2-on

: 63859-99-4
(14R,all-E)-14,15-Epoxy-3,7,11,15-tetramethyl-1-(phenylthio)hexadeca-2,6,10-trien

Guidance literature:: Multi-step reaction with 10 steps

1: 28 percent / SeO₂, tert-butyl-hydroperoxid (TBHP) / CH₂Cl₂; H₂O / 18 h / 0 °C

2: 92 percent / tetrahydrofuran / 4 h / Ambient temperature

3: 95 percent / pyridin / 2 h

4: PBr₃, pyridine / petroleum ether / 3 h / -17 °C

5: 45 percent / dimethylformamide / 16 h / 60 °C

6: 80 percent / K₂CO₃ / methanol / 3 h / Ambient temperature

7: 57 percent / tert-Butyl-hydroperoxid (TBHP), Molekularsieb 4 Angstroem, Ti(i-OPr)4, (-)-D-Diethyl-tartrat / CH₂Cl₂; toluene / 4 h / -40 - -20 °C

8: 81 percent / Pyridin / 16 h / 0 °C

9: NaI / acetone / 2 h / 60 °C

10: 48 percent / Na(BH₃CN) / tetrahydrofuran; hexamethylphosphoric acid triamide / 24 h / Ambient temperature

With pyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; selenium(IV) oxide; Molekularsieb 4 Angstroem; phosphorus tribromide; sodium cyanoborohydride; potassium carbonate; (-)-diethyl tartrate; sodium iodide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; Petroleum ether;
DOI:10.1002/hlca.19900730721

Reference yield:

: 132273-99-5
(all-E)-15-Hydroxy-6,10,14-trimethylpentadeca-5,9,13-trien-2-on

: 63859-99-4
(14R,all-E)-14,15-Epoxy-3,7,11,15-tetramethyl-1-(phenylthio)hexadeca-2,6,10-trien

Guidance literature:: Multi-step reaction with 9 steps

1: 92 percent / tetrahydrofuran / 4 h / Ambient temperature

2: 95 percent / pyridin / 2 h

3: PBr₃, pyridine / petroleum ether / 3 h / -17 °C

4: 45 percent / dimethylformamide / 16 h / 60 °C

5: 80 percent / K₂CO₃ / methanol / 3 h / Ambient temperature

6: 57 percent / tert-Butyl-hydroperoxid (TBHP), Molekularsieb 4 Angstroem, Ti(i-OPr)4, (-)-D-Diethyl-tartrat / CH₂Cl₂; toluene / 4 h / -40 - -20 °C

7: 81 percent / Pyridin / 16 h / 0 °C

8: NaI / acetone / 2 h / 60 °C

9: 48 percent / Na(BH₃CN) / tetrahydrofuran; hexamethylphosphoric acid triamide / 24 h / Ambient temperature

With pyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; Molekularsieb 4 Angstroem; phosphorus tribromide; sodium cyanoborohydride; potassium carbonate; (-)-diethyl tartrate; sodium iodide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; N,N-dimethyl-formamide; acetone; toluene; Petroleum ether;
DOI:10.1002/hlca.19900730721