sodium piperidin-1-yldithiocarbamate

Base Information

• Chemical Name: sodium piperidin-1-yldithiocarbamate
• CAS No.: 29053-42-7
• Molecular Formula: C6H12 N2 S2 . Na
• Molecular Weight: 198.289
• Mol file: 29053-42-7.mol

Synonyms:1-Piperidinecarbamicacid, dithio-, monosodium salt (8CI)

Chemical Property of sodium piperidin-1-yldithiocarbamate

Chemical Property:

• Vapor Pressure: 0.0311mmHg at 25°C
• Boiling Point: 244°Cat760mmHg
• Flash Point: 101.4°C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of sodium piperidin-1-yldithiocarbamate

There total 1 articles about sodium piperidin-1-yldithiocarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.5%

carbon disulfide (75-15-0,12122-00-8) + 1-Aminopiperidine (2213-43-6) → sodium piperidin-1-ylcarbamodithioate (29053-42-7)

Guidance literature:

With sodium hydroxide; In water; ethyl acetate; at 0 - 20 ℃; for 3h;

DOI:10.1016/j.bmcl.2014.10.040

Reference yield: 85.0%

uranyl nirate hexahydrate + sodium piperidin-1-ylcarbamodithioate (29053-42-7) + Triphenylphosphine oxide (791-28-6) → bis(N-piperidyldithiocarbamato)dioxo(triphenylphosphine oxide)uranium(VI)

Guidance literature:

In methanol; dimethyl sulfoxide; byproducts: sodium nitrate; a soln. of 1 equiv of UO2(NO3)2*6H2O in MeOH-DMSO was treated with 1 equiv of Ph3PO and 2 equiv of PipNCS2Na, stirred for 30 min at room. temp.; filtered, pptd. by adding H2O to the filtrate, filtered by suction, washed with H2O, dried over CaCl2 under vac., purified by dissolving in MeOH-DMSO and reprecipitating with H2O; elem. anal.;

DOI:10.1016/S0020-1693(00)84474-6

Reference yield: 71.0%

sodium piperidin-1-ylcarbamodithioate (29053-42-7) + benzyl chloride (100-44-7) → benzyl piperidin-1-ylcarbamodithioate

Guidance literature:

In water; for 0.5h; Green chemistry;

DOI:10.1016/j.bmcl.2014.10.040

upstream raw materials:

carbon disulfide

1-Aminopiperidine

Refernces