CHLOROFERROCENE

Base Information

• Chemical Name: CHLOROFERROCENE
• CAS No.: 1273-74-1
• Molecular Formula: C10H9 Cl Fe
• Molecular Weight: 220.481
• Mol file: 1273-74-1.mol

Synonyms:Iron,(chlorocyclopentadienyl)cyclopentadienyl- (6CI,7CI); 1-Chloroferrocene;Chloroferrocene

Chemical Property of CHLOROFERROCENE

Chemical Property:

• Boiling Point: 129°Cat760mmHg
• Flash Point: 12.4°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.90220
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 219.974214
• Heavy Atom Count: 12
• Complexity: 128

Purity/Quality:

98%min ^*data from raw suppliers

Chloroferrocene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH-]1[CH-][CH-][CH-][CH-]1.C1=C[C-](C=C1)Cl.[Fe]

Technology Process of CHLOROFERROCENE

There total 40 articles about CHLOROFERROCENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1'-chloroferrocenylsilver → chloroferrocene (1273-74-1)

Guidance literature:

With hydrogen sulfide; In benzene; in abs. benzene;;

Reference yield: 88.3%

iodoferrocene (1273-76-3) + copper(l) chloride → chloroferrocene (1273-74-1)

Guidance literature:

In pyridine; in boiling pyridine;;

Reference yield: 85.0%

ferrocene (102-54-5,55404-68-7) + hexachloroethane (67-72-1) → chloroferrocene (1273-74-1)

Guidance literature:

ferrocene; With potassium tert-butylate; tert.-butyl lithium; In tetrahydrofuran; at -78 ℃; for 1.25h; Inert atmosphere; Schlenk technique;

hexachloroethane; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1039/d0nj05334a

upstream raw materials:

benzylidene dichloride

ferrocene

benzyl chloride

Benzotrichlorid

Downstream raw materials:

ferrocene

lithiumferrocene

acetylferrocene

isopropoxyferrocene