Technology Process of 2-Pentenoic acid, 3,4-dimethyl-, ethyl ester
There total 1 articles about 2-Pentenoic acid, 3,4-dimethyl-, ethyl ester which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
1,2-dimethyl-1H-imidazole;
In
diethyl ether;
at 51 ℃;
Quantum yield;
Product distribution;
Mechanism;
Irradiation;
with 3,4-dimethyl derivatives, other products; other solvents, without base;
DOI:10.1139/v84-332
- Guidance literature:
-
Multi-step reaction with 2 steps
1: diisobutylaluminium hydride / tetrahydrofuran; hexane / 3 h / -78 °C
2: phosphorus tribromide / dichloromethane / 1 h / 0 °C
With
phosphorus tribromide; diisobutylaluminium hydride;
In
tetrahydrofuran; hexane; dichloromethane;
DOI:10.1039/c5ob00594a
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: diisobutylaluminium hydride / tetrahydrofuran; hexane / 3 h / -78 °C
2.1: phosphorus tribromide / dichloromethane / 1 h / 0 °C
3.1: isopropylmagnesium chloride; lithium chloride / tetrahydrofuran / 3 h / -30 °C / Inert atmosphere; Schlenk technique
3.2: 24 h / -40 °C / Inert atmosphere; Schlenk technique
With
isopropylmagnesium chloride; phosphorus tribromide; diisobutylaluminium hydride; lithium chloride;
In
tetrahydrofuran; hexane; dichloromethane;
DOI:10.1039/c5ob00594a
