Propan-2-yl dicyclohexylphosphinite

Base Information

• Chemical Name: Propan-2-yl dicyclohexylphosphinite
• CAS No.: 65796-69-2
• Molecular Formula: C15H29OP
• Molecular Weight: 256.368
• DSSTox Substance ID: DTXSID60561602
• Wikidata: Q82445443
• Mol file: 65796-69-2.mol

Synonyms:Propan-2-yl dicyclohexylphosphinite;65796-69-2;SCHEMBL3958447;DTXSID60561602

Chemical Property of Propan-2-yl dicyclohexylphosphinite

Chemical Property:

• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 256.195602542
• Heavy Atom Count: 17
• Complexity: 187

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)OP(C1CCCCC1)C2CCCCC2

Technology Process of Propan-2-yl dicyclohexylphosphinite

There total 1 articles about Propan-2-yl dicyclohexylphosphinite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

isopropyl alcohol (67-63-0,8013-70-5) + chlorodicyclohexylphosphane (16523-54-9) → Dicyclohexyl-isopropyloxy-phosphin (65796-69-2)

Guidance literature:

With triethylamine; In benzene; Heating;

DOI:10.1002/hlca.19770600835

Reference yield: 68.0%

1,3-bis(2,4,6-trimethylphenyl)-2-(trichloromethyl)imidazolidine + Dicyclohexyl-isopropyloxy-phosphin (65796-69-2) + dichloro(3-methyl-2-butenylidene)bis(triphenylphosphine)ruthenium → C41H63Cl2N2OPRu

Guidance literature:

Dicyclohexyl-isopropyloxy-phosphin; dichloro(3-methyl-2-butenylidene)bis(triphenylphosphine)ruthenium; In tetrahydrofuran; at 20 ℃; for 0.25h;

1,3-bis(2,4,6-trimethylphenyl)-2-(trichloromethyl)imidazolidine; With [CAS 260054-47-5]; In tetrahydrofuran; at 65 ℃; for 2h;

Reference yield:

Dicyclohexyl-isopropyloxy-phosphin (65796-69-2) → 1,11-Bis-(dicyclohexylphosphinomethyl)-benzophenanthren (65796-62-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 140 - 170 °C

2: HSiCl₃, nBu₃N / acetonitrile / Heating

With tributyl-amine; trichlorosilane; In acetonitrile;

DOI:10.1002/hlca.19770600835

upstream raw materials:

isopropyl alcohol

chlorodicyclohexylphosphane

Downstream raw materials:

1,11-Bis-(dicyclohexylphosphorylmethyl)-benzophenanthren

1,11-Bis-(dicyclohexylphosphinomethyl)-benzophenanthren