Psilostachyin C

Base Information

Chemical Name:Psilostachyin C
CAS No.:6466-67-7
Deprecated CAS:20554-85-2
Molecular Formula:C₁₅H₂₀O₄
Molecular Weight:264.321
Hs Code.:
NSC Number:106392,247515
Wikidata:Q82970197

Synonyms:psilostachyin C

Suppliers and Price of Psilostachyin C

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Psilostachyin C

Chemical Property:

Boiling Point:461.4°Cat760mmHg
Flash Point:239.2°C
PSA：52.60000
Density:1.17g/cm³
LogP:2.22600
XLogP3:2.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:264.13615911
Heavy Atom Count:19
Complexity:455

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1CCC2C(C3(C1CCC(=O)O3)C)OC(=O)C2=C

Technology Process of Psilostachyin C

There total 15 articles about Psilostachyin C which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 60133-11-1
rac-damsin

: 6466-67-7,64813-80-5
(+/-)-Psilostachyin

Guidance literature:: With bis-trimethylsilanyl peroxide; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -78 - -50 ℃; for 24h; Inert atmosphere;
DOI:10.1021/jo2001275

Reference yield:

: C₁₉H₃₀O₄

: 6466-67-7,64813-80-5
(+/-)-Psilostachyin

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride / tetrahydrofuran; mineral oil / 0.25 h / 100 °C / Sealed tube; Inert atmosphere

2: hydrogenchloride / tetrahydrofuran / 20 h / 20 °C / Inert atmosphere

3: bis-trimethylsilanyl peroxide; trimethylsilyl trifluoromethanesulfonate / dichloromethane / 24 h / -78 - -50 °C / Inert atmosphere

With hydrogenchloride; bis-trimethylsilanyl peroxide; trimethylsilyl trifluoromethanesulfonate; sodium hydride; In tetrahydrofuran; dichloromethane; mineral oil; 3: Baeyer-Villiger oxidation;
DOI:10.1021/jo2001275

Reference yield:

: C₂₀H₃₀O₄

: 6466-67-7,64813-80-5
(+/-)-Psilostachyin

Guidance literature:: Multi-step reaction with 2 steps

1: hydrogenchloride / tetrahydrofuran / 20 h / 20 °C / Inert atmosphere

2: bis-trimethylsilanyl peroxide; trimethylsilyl trifluoromethanesulfonate / dichloromethane / 24 h / -78 - -50 °C / Inert atmosphere

With hydrogenchloride; bis-trimethylsilanyl peroxide; trimethylsilyl trifluoromethanesulfonate; In tetrahydrofuran; dichloromethane; 2: Baeyer-Villiger oxidation;
DOI:10.1021/jo2001275