2-Hexanone, (2,4-dinitrophenyl)hydrazone

Base Information

• Chemical Name: 2-Hexanone, (2,4-dinitrophenyl)hydrazone
• CAS No.: 2348-17-6
• Molecular Formula: C₁₂H₁₆N₄O₄
• Molecular Weight: 280.283
• NSC Number: 61884
• Mol file: 2348-17-6.mol

Synonyms:2-Hexanone, (2,4-dinitrophenyl)hydrazone;2-Hexanone (2,4-dinitrophenyl)hydrazone;NSC61884;(2E)-2-Hexanone (2,4-dinitrophenyl)hydrazone #;ZQAHBVPRAUEYPQ-UKTHLTGXSA-N;2348-17-6;2-Hexanone,4-dinitrophenyl)hydrazone;NSC-61884;(2E)-2-Hexanone (2,4-dinitrophenyl)hydrazone

Chemical Property of 2-Hexanone, (2,4-dinitrophenyl)hydrazone

Chemical Property:

• Vapor Pressure: 8.37E-07mmHg at 25°C
• Boiling Point: 406.1°Cat760mmHg
• Flash Point: 199.4°C
• PSA: 116.03000
• Density: 1.29g/cm³
• LogP: 4.60040
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 5
• Exact Mass: 280.11715500
• Heavy Atom Count: 20
• Complexity: 375

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC(=NNC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])C
• Isomeric SMILES: CCCC/C(=N/NC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])/C

Technology Process of 2-Hexanone, (2,4-dinitrophenyl)hydrazone

There total 17 articles about 2-Hexanone, (2,4-dinitrophenyl)hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hex-1-yne (693-02-7) → hexan-2-one-(2,4-dinitro-phenylhydrazone) (2348-17-6,74335-87-8,74335-88-9)

Guidance literature:

Multi-step reaction with 2 steps

1: water; H₃PO₄-kieselguhr / 204 °C

With H₃PO₄-kieselguhr; water;

Reference yield:

n-hexan-2-one (591-78-6) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → hexan-2-one-(2,4-dinitro-phenylhydrazone) (2348-17-6,74335-87-8,74335-88-9)

Guidance literature:

DOI:10.1039/jr9460000052

Reference yield:

pentyl phenyl sulfide (1129-70-0) → hexan-2-one-(2,4-dinitro-phenylhydrazone) (2348-17-6,74335-87-8,74335-88-9)

Guidance literature:

Multi-step reaction with 6 steps

1: m-chloroperbenzoic acid

2: 81 percent / butyl-lithium / hexane; tetrahydrofuran / 1 h / 0 °C

3: 82 percent / butyl-lithium / hexane; tetrahydrofuran / 0 °C

4: 79 percent / di-isobutylaluminum hydride / toluene / 48 h / Heating

5: 85percent m-chloroperbenzoic acid / CH₂Cl₂ / 1.5 h / -23 °C

With n-butyllithium; diisobutylaluminum hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; hexane; dichloromethane; toluene;

DOI:10.1039/P19860000195

upstream raw materials:

n-hexan-2-one

(2,4-dinitro-phenyl)-hydrazine

2-ethoxy-1-hexene

n-hexan-2-ol