3,5,6,8-Tetrabromo-1,10-phenanthroline

Base Information

Chemical Name:3,5,6,8-Tetrabromo-1,10-phenanthroline
CAS No.:66127-00-2
Molecular Formula:C12H4Br4N2
Molecular Weight:495.79000
Hs Code.:2933990090
European Community (EC) Number:633-152-7
DSSTox Substance ID:DTXSID60466007
Nikkaji Number:J2.104.842I
Wikidata:Q82292365

Synonyms:3,5,6,8-tetrabromo-1,10-phenanthroline;66127-00-2;SCHEMBL7059861;DTXSID60466007;BAPJVWLAFSQLNX-UHFFFAOYSA-N;MFCD09879848;AKOS025394796;CS-0087113;T3133;D92665;3,5,6,8-Tetrabromo-1,10-phenanthroline, 95%

Suppliers and Price of 3,5,6,8-Tetrabromo-1,10-phenanthroline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
3,5,6,8-Tetrabromo-1,10-phenanthroline >95.0%(HPLC)
100mg
$ 204.00

Strem Chemicals
3,5,6,8-Tetrabromo-1,10-phenanthroline, 98%
1g
$ 280.00

Strem Chemicals
3,5,6,8-Tetrabromo-1,10-phenanthroline, 98%
250mg
$ 93.00

Sigma-Aldrich
3,5,6,8-Tetrabromo-1,10-phenanthroline 95%
250mg
$ 74.80

Sigma-Aldrich
3,5,6,8-Tetrabromo-1,10-phenanthroline 95%
1g
$ 229.00

Chem-Impex
3,5,6,8-Tetrabromo-1,10-phenanthroline,99%(Assaybytitration) 99%(Assaybytitration)
100MG
$ 243.04

Arctom
3,5,6,8-Tetrabromo-1,10-phenanthroline 98%
250mg
$ 217.00

Arctom
3,5,6,8-Tetrabromo-1,10-phenanthroline 98%
100mg
$ 146.00

Arctom
3,5,6,8-Tetrabromo-1,10-phenanthroline 98%
1g
$ 542.00

American Custom Chemicals Corporation
3,5,6,8-TETRABROMO-1,10-PHENANTHROLINE 95.00%
1G
$ 844.68

Total 12 raw suppliers

Chemical Property of 3,5,6,8-Tetrabromo-1,10-phenanthroline

Chemical Property:

Melting Point:356°C(lit.)
Boiling Point:523.2±45.0 °C(Predicted)
PKA:2.21±0.10(Predicted)
PSA：25.78000
Density:2.373±0.06 g/cm3(Predicted)
LogP:5.83300
XLogP3:5.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:495.70670
Heavy Atom Count:18
Complexity:287

Purity/Quality:

97% ^*data from raw suppliers

3,5,6,8-Tetrabromo-1,10-phenanthroline >95.0%(HPLC) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 41
Safety Statements: 26-39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=C(C=NC2=C1C(=C(C3=C2N=CC(=C3)Br)Br)Br)Br
Uses 3,5,6,8-Tetrabromo-1,10-phenanthroline can be used in the nickel-catalyzed amination of aryl and heteroaryl chlorides.

Technology Process of 3,5,6,8-Tetrabromo-1,10-phenanthroline

There total 7 articles about 3,5,6,8-Tetrabromo-1,10-phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 66-71-7
1,10-Phenanthroline

: 66127-00-2
3,5,6,8-tetrabromo-1,10-phenanthroline

Guidance literature:: With thionyl chloride; bromine; for 31h; Heating;
DOI:10.1002/ejic.200400163

Reference yield: 19.0%

: 66-71-7
1,10-Phenanthroline

: 66127-00-2
3,5,6,8-tetrabromo-1,10-phenanthroline

: 202601-20-5
3,5,8-tribromo-1,10-phenanthroline

Guidance literature:: With pyridine; sulfur dichloride; bromine; at 105 - 110 ℃; for 12h; Inert atmosphere;
DOI:10.1071/CH13711

Reference yield:

: 24108-97-2
3,4-dibromoacetanilide

: 66127-00-2
3,5,6,8-tetrabromo-1,10-phenanthroline

Guidance literature:: Multi-step reaction with 4 steps

1: H₂SO₄

2: arsenic acid; aqueous sulfuric acid

3: iron; aqueous acetic acid

4: H₃aso4; aqueous H₂SO₄

With sulfuric acid; orthoarsenic acid; iron; acetic acid;
DOI:10.1021/jo01146a018