Benzenemethanol, 4-(methoxymethyl)-a-methyl-

Base Information

Chemical Name:Benzenemethanol, 4-(methoxymethyl)-a-methyl-
CAS No.:66190-31-6
Molecular Formula:C₁₀H₁₄O₂
Molecular Weight:166.22
Hs Code.:

Synonyms:

Suppliers and Price of Benzenemethanol, 4-(methoxymethyl)-a-methyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Rieke Metals
1-(4-METHOXYMETHYLPHENYL)ETHANOL
5g
$ 1943.00

Rieke Metals
1-(4-METHOXYMETHYLPHENYL)ETHANOL
1g
$ 809.00

Total 3 raw suppliers

Chemical Property of Benzenemethanol, 4-(methoxymethyl)-a-methyl-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

1-(4-METHOXYMETHYLPHENYL)ETHANOL ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Benzenemethanol, 4-(methoxymethyl)-a-methyl-

There total 8 articles about Benzenemethanol, 4-(methoxymethyl)-a-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 22072-50-0
1-(4-(methoxymethyl)phenyl)ethanone

: 66190-31-6
(+)-1-(4-methoxymethylphenyl)ethanol

: 66190-31-6
(-)-1-(4-methoxymethylphenyl)ethanol

Guidance literature:: With trans-[Ru((R)-3,5-xylyl-BINAP)(Cl₂)((R)-DAIPEN)]; potassium tert-butylate; hydrogen; In isopropyl alcohol; at 20 ℃; for 13h; under 3040.2 Torr; optical yield given as %ee; Autoclave;
DOI:10.1021/ja202732q

Reference yield:

: 22072-50-0
1-(4-(methoxymethyl)phenyl)ethanone

: 66190-31-6
(+)-1-(4-methoxymethylphenyl)ethanol

: 66190-31-6
(-)-1-(4-methoxymethylphenyl)ethanol

Guidance literature:: With trans-[Ru((R)-3,5-xylyl-BINAP)(Cl₂)((R)-DAIPEN)]; potassium tert-butylate; hydrogen; In isopropyl alcohol; at 20 ℃; for 13h; under 3040.2 Torr; optical yield given as %ee; Autoclave;
DOI:10.1021/ja202732q

Reference yield:

: C₁₂H₁₆O₃

: 66190-31-6
(+)-1-(4-methoxymethylphenyl)ethanol

: 66190-31-6
(-)-1-(4-methoxymethylphenyl)ethanol

Guidance literature:: Multi-step reaction with 2 steps

1: hydrogenchloride; water / tetrahydrofuran; mineral oil / Inert atmosphere

2: trans-[Ru((R)-3,5-xylyl-BINAP)(Cl₂)((R)-DAIPEN)]; potassium tert-butylate; hydrogen / isopropyl alcohol / 13 h / 20 °C / 3040.2 Torr / Autoclave

With hydrogenchloride; trans-[Ru((R)-3,5-xylyl-BINAP)(Cl₂)((R)-DAIPEN)]; potassium tert-butylate; water; hydrogen; In tetrahydrofuran; isopropyl alcohol; mineral oil;
DOI:10.1021/ja202732q