Benzeneacetic acid, a-cyano-a-2-propenyl-, ethyl ester

Base Information

Chemical Name:Benzeneacetic acid, a-cyano-a-2-propenyl-, ethyl ester
CAS No.:66205-43-4
Molecular Formula:C14H15NO2
Molecular Weight:229.279
Hs Code.:

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Chemical Property of Benzeneacetic acid, a-cyano-a-2-propenyl-, ethyl ester

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Technology Process of Benzeneacetic acid, a-cyano-a-2-propenyl-, ethyl ester

There total 4 articles about Benzeneacetic acid, a-cyano-a-2-propenyl-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 24850-33-7
allyltributylstanane

: 4553-07-5
ethyl phenylcyanoacetate

: 66205-43-4
cyano-allyl-phenyl-acetic acid ethyl ester

Guidance literature:: With (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In dichloromethane; for 48h; Ambient temperature;
DOI:10.1039/c39950002013

Reference yield: 77.0%

: 3509-01-1
2-cyano-pent-4-enoic acid ethyl ester

: 66003-76-7
Diphenyliodonium triflate

: 66205-43-4
cyano-allyl-phenyl-acetic acid ethyl ester

Guidance literature:: 2-cyano-pent-4-enoic acid ethyl ester; With potassium tert-butylate; In dichloromethane; at 0 ℃; for 0.0833333h; Schlenk technique; Inert atmosphere;

Diphenyliodonium triflate; In dichloromethane; at 0 ℃; for 0.333333h; Schlenk technique; Inert atmosphere;
DOI:10.1002/adsc.201501013

Reference yield: 74.0%

: 108-86-1,52753-63-6
bromobenzene

: 106-95-6
allyl bromide

: 105-56-6
ethyl 2-cyanoacetate

: 66205-43-4
cyano-allyl-phenyl-acetic acid ethyl ester

Guidance literature:: bromobenzene; ethyl 2-cyanoacetate; With 1,1'-bis-(diphenylphosphino)ferrocene; potassium tert-butylate; palladium diacetate; In 1,4-dioxane; at 70 ℃;

allyl bromide; In 1,4-dioxane; at 20 ℃; for 2h; Further stages.;
DOI:10.1021/jo7024338