4-[Ethenyl(dimethyl)silyl]benzoic acid

Base Information

Chemical Name:4-[Ethenyl(dimethyl)silyl]benzoic acid
CAS No.:66259-07-2
Molecular Formula:C11H14O2Si
Molecular Weight:206.316
Hs Code.:
DSSTox Substance ID:DTXSID80572679
Wikidata:Q82461105

Synonyms:66259-07-2;4-[Ethenyl(dimethyl)silyl]benzoic acid;DTXSID80572679

Suppliers and Price of 4-[Ethenyl(dimethyl)silyl]benzoic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 4-[Ethenyl(dimethyl)silyl]benzoic acid

Chemical Property:

Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:206.076306220
Heavy Atom Count:14
Complexity:227

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C=C)C1=CC=C(C=C1)C(=O)O

Technology Process of 4-[Ethenyl(dimethyl)silyl]benzoic acid

There total 4 articles about 4-[Ethenyl(dimethyl)silyl]benzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1719-58-0
Chlorodimethylvinylsilane

: 586-76-5
4-Bromobenzoic acid

: 66259-07-2
4-(vinyldimethylsilyl)benzoic acid

Guidance literature:: 4-Bromobenzoic acid; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

Chlorodimethylvinylsilane; In tetrahydrofuran; hexane; at -78 ℃; for 12h;

With hydrogenchloride; water; In tetrahydrofuran; hexane; ethyl acetate;

Reference yield:

: 221238-61-5
2-<4-(vinyldimethylsilyl)phenyl>-4,4-dimethyloxazoline

: 66259-07-2
4-(vinyldimethylsilyl)benzoic acid

Guidance literature:: Multi-step reaction with 2 steps

1: acetonitrile / 48 h / 120 °C

2: aq. NaOH / 24 h / Ambient temperature

With sodium hydroxide; In acetonitrile;
DOI:10.1016/S0040-4020(98)01207-1