Benzenemethanol, 2-[(1Z)-2-[2-[(1Z)-2-[2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phen yl]ethenyl]phenyl]ethenyl]-

Base Information

• Chemical Name: Benzenemethanol, 2-[(1Z)-2-[2-[(1Z)-2-[2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phen yl]ethenyl]phenyl]ethenyl]-
• CAS No.: 664335-53-9
• Molecular Formula: C₃₀H₃₆O₂Si
• Molecular Weight: 456.7
• Mol file: 664335-53-9.mol

Synonyms:

Chemical Property of Benzenemethanol, 2-[(1Z)-2-[2-[(1Z)-2-[2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phen yl]ethenyl]phenyl]ethenyl]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzenemethanol, 2-[(1Z)-2-[2-[(1Z)-2-[2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phen yl]ethenyl]phenyl]ethenyl]-

There total 1 articles about Benzenemethanol, 2-[(1Z)-2-[2-[(1Z)-2-[2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]phen yl]ethenyl]phenyl]ethenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ortho-bromobenzaldehyde (6630-33-7) + tert-butyl-{2-[2-(2-ethynyl-phenyl)-vinyl]-benzyloxy}-dimethyl-silane (261720-14-3) → {2-[(Z)-2-(2-{(Z)-2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-vinyl}-phenyl)-vinyl]-phenyl}-methanol (664335-53-9)

Guidance literature:

ortho-bromobenzaldehyde; tert-butyl-{2-[2-(2-ethynyl-phenyl)-vinyl]-benzyloxy}-dimethyl-silane; With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; for 0.166667h; Heating;

With sodium tetrahydroborate; In ethanol;

With quinoline; hydrogen; Lindlar's catalyst; In ethanol; benzene; Further stages.;

DOI:10.1016/j.tetlet.2003.10.163

Reference yield:

{2-[(Z)-2-(2-{(Z)-2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-vinyl}-phenyl)-vinyl]-phenyl}-methanol (664335-53-9) → 2-[(Z)-2-(2-{(Z)-2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-vinyl}-phenyl)-vinyl]-benzaldehyde (664335-54-0)

Guidance literature:

With Dess-Martin periodane; In dichloromethane;

DOI:10.1016/j.tetlet.2003.10.163

upstream raw materials:

ortho-bromobenzaldehyde

tert-butyl-{2-[2-(2-ethynyl-phenyl)-vinyl]-benzyloxy}-dimethyl-silane

Downstream raw materials:

2-[(Z)-2-(2-{(Z)-2-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-phenyl]-vinyl}-phenyl)-vinyl]-benzaldehyde