2,3-Dimethylidenebicyclo[2.2.1]heptan-7-one

Base Information

Chemical Name:2,3-Dimethylidenebicyclo[2.2.1]heptan-7-one
CAS No.:38680-06-7
Molecular Formula:C₉H₁₀O
Molecular Weight:134.178
Hs Code.:
DSSTox Substance ID:DTXSID30959517
Mol file:38680-06-7.mol

Synonyms:38680-06-7;2,3-dimethylidenebicyclo[2.2.1]heptan-7-one;Bicyclo[2.2.1]heptan-7-one,2,3-bis(methylene)-;Bicyclo(2.2.1)heptan-7-one, 2,3-bis(methylene)-;DTXSID30959517

Suppliers and Price of 2,3-Dimethylidenebicyclo[2.2.1]heptan-7-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 2,3-Dimethylidenebicyclo[2.2.1]heptan-7-one

Chemical Property:

Vapor Pressure:0.146mmHg at 25°C
Boiling Point:215.7°Cat760mmHg
Flash Point:81.8°C
Density:1.04g/cm³
XLogP3:1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:134.073164938
Heavy Atom Count:10
Complexity:213

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=C1C2CCC(C1=C)C2=O

Technology Process of 2,3-Dimethylidenebicyclo[2.2.1]heptan-7-one

There total 8 articles about 2,3-Dimethylidenebicyclo[2.2.1]heptan-7-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

: 7,7-dimethoxy-2,3-dimethylidenebicyclo<2.2.1>heptane

: 38680-06-7
2,3-dimethylidenebicyclo<2.2.1>heptan-7-one

Guidance literature:: In water; acetic acid; at 60 ℃; for 48h;
DOI:10.1002/hlca.19850680130

Reference yield:

: 15208-02-3
endo-1,4,5,6-tetrachloro-7,7-dimethoxy-2,3-bis-hydroxymethylbicyclo[2.2.1]hept-5-ene

: 38680-06-7
2,3-dimethylidenebicyclo<2.2.1>heptan-7-one

Guidance literature:: Multi-step reaction with 6 steps

1: 80 percent / TsOH*H₂O / CHCl₃; H₂O / 72 h / Heating

2: 49 percent / Na / methanol / 3 h / Heating

3: 93 percent / H₂ / 10percent Pd / methanol / 72 h / 2660 Torr

4: pyridine

5: 47 percent / t-BuOK / tetrahydrofuran

6: 24 percent / acetic acid; H₂O / 48 h / 60 °C

With potassium tert-butylate; hydrogen; sodium; toluene-4-sulfonic acid; palladium; In tetrahydrofuran; pyridine; methanol; chloroform; water; acetic acid;
DOI:10.1002/hlca.19850680130

Reference yield:

: 20379-81-1
endo-1,7,8,9-tetrachloro-10,10-dimethoxy-4-oxatricyclo[5.2.1.0^2,6]dec-8-ene-3,5-dione

: 38680-06-7
2,3-dimethylidenebicyclo<2.2.1>heptan-7-one

Guidance literature:: Multi-step reaction with 7 steps

1: LiAlH₄ / tetrahydrofuran / 12 h / Heating

2: 80 percent / TsOH*H₂O / CHCl₃; H₂O / 72 h / Heating

3: 49 percent / Na / methanol / 3 h / Heating

4: 93 percent / H₂ / 10percent Pd / methanol / 72 h / 2660 Torr

5: pyridine

6: 47 percent / t-BuOK / tetrahydrofuran

7: 24 percent / acetic acid; H₂O / 48 h / 60 °C

With lithium aluminium tetrahydride; potassium tert-butylate; hydrogen; sodium; toluene-4-sulfonic acid; palladium; In tetrahydrofuran; pyridine; methanol; chloroform; water; acetic acid;
DOI:10.1002/hlca.19850680130