(2,6-Dichlorophenyl)hydrazine

Base Information

• Chemical Name: (2,6-Dichlorophenyl)hydrazine
• CAS No.: 14763-24-7
• Molecular Formula: C6H6 Cl2 N2
• Molecular Weight: 177.033
• Hs Code.: 2928000090
• European Community (EC) Number: 238-825-5
• NSC Number: 512286
• UNII: ZR5C8QGQ8J
• DSSTox Substance ID: DTXSID20163762
• Nikkaji Number: J141.362G
• Wikidata: Q83032761
• Mol file: 14763-24-7.mol

Synonyms:(2,6-Dichlorophenyl)hydrazine;14763-24-7;2,6-DICHLOROPHENYLHYDRAZINE;Hydrazine, (2,6-dichlorophenyl)-;1-(2,6-Dichlorophenyl)hydrazine;EINECS 238-825-5;NSC-512286;2,6-Dichlorophenylhydrazinehydrochloride;NSC512286;N(N)c1c(Cl)cccc1Cl;ZR5C8QGQ8J;2,6 dichlorophenyl hydrazine;2,6-dichloro-phenylhydrazine;SCHEMBL1144086;DTXSID20163762;(2,6-Dichloro-phenyl)-hydrazine;1-(2,6-Dichlorophenyl)hydrazine #;BBL022190;MFCD00044516;STK894831;AKOS001475953;NSC 512286;A7521;BB 0249760;FT-0741436

Chemical Property of (2,6-Dichlorophenyl)hydrazine

Chemical Property:

• Vapor Pressure: 0.0182mmHg at 25°C
• Melting Point: 100.5-101.5 °C
• Boiling Point: 253.5°Cat760mmHg
• PKA: 4.01±0.13(Predicted)
• Flash Point: 107.1°C
• PSA: 38.05000
• Density: 1.475g/cm³
• LogP: 3.05230
• XLogP3: 2.2
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 175.9908036
• Heavy Atom Count: 10
• Complexity: 99.9

Purity/Quality:

98%min ^*data from raw suppliers

(2,6-Dichlorophenyl)hydrazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=C(C(=C1)Cl)NN)Cl

Technology Process of (2,6-Dichlorophenyl)hydrazine

There total 5 articles about (2,6-Dichlorophenyl)hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(2,6-dichlorophenyl)hydrazine monohydrochloride (50709-36-9) → (2,6-dichlorophenyl)hydrazine (14763-24-7)

Guidance literature:

With sodium hydroxide; water; sodium hydrogencarbonate;

Reference yield: 63.4%

2,6-Dichloroaniline (608-31-1) → (2,6-dichlorophenyl)hydrazine (14763-24-7)

Guidance literature:

2,6-Dichloroaniline; With hydrogenchloride; sodium nitrite; at 0 ℃; for 0.5h;

With tin(ll) chloride; at 0 ℃; for 2h;

DOI:10.1016/j.bmc.2018.05.028

Reference yield:

→ (2,6-dichlorophenyl)hydrazine (14763-24-7)

Guidance literature:

With hydrogenchloride; tin(ll) chloride; Behandeln des Reaktionsprodukts mit wss. Natronlauge;

upstream raw materials:

2,6-Dichloro-benzenediazonium; chloride

2,6-Dichloroaniline

(2,6-dichlorophenyl)hydrazine monohydrochloride

Downstream raw materials:

5-Methyl-2H-pyrazole-3-carboxylic acid N'-(2,6-dichloro-phenyl)-hydrazide

phthalaldehydic acid phenylhydrazone

(E)-1-benzylidene-2-phenylhydrazine

Refernces

• 1、 Nikovskiy, Igor,Polezhaev, Alexander,Novikov, Valentin,Aleshin, Dmitry,Pavlov, Alexander,Saffiulina, Elnara,Aysin, Rinat,Dorovatovskii, Pavel,Nodaraki, Lydia,Tuna, Floriana,Nelyubina, Yulia. "Towards the Molecular Design of Spin-Crossover Complexes of 2,6-Bis(pyrazol-3-yl)pyridines". . p. 5629 - 5638. Retrieved 2020/03/23.
• 2、 Wang, Xing,Chen, Yong-Fei,Yan, Wei,Cao, Ling-Ling,Ye, Yong-Hao. "Synthesis and biological evaluation of benzimidazole phenylhydrazone derivatives as antifungal agents against phytopathogenic fungi". . . Retrieved 2016/12/03.