Quinoline, 5,5'-(1H-pyrrole-3,4-diyl)bis[7,8-bis(phenylmethoxy)-

Base Information

Chemical Name:Quinoline, 5,5'-(1H-pyrrole-3,4-diyl)bis[7,8-bis(phenylmethoxy)-
CAS No.:671788-47-9
Molecular Formula:C₅₀H₃₉N₃O₄
Molecular Weight:745.877
Hs Code.:

Synonyms:

Suppliers and Price of Quinoline, 5,5'-(1H-pyrrole-3,4-diyl)bis[7,8-bis(phenylmethoxy)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Quinoline, 5,5'-(1H-pyrrole-3,4-diyl)bis[7,8-bis(phenylmethoxy)-

Chemical Property:

Purity/Quality:: 95% ^*data from raw suppliers

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Hazard Codes:

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Technology Process of Quinoline, 5,5'-(1H-pyrrole-3,4-diyl)bis[7,8-bis(phenylmethoxy)-

There total 5 articles about Quinoline, 5,5'-(1H-pyrrole-3,4-diyl)bis[7,8-bis(phenylmethoxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 671788-59-3
bis-3,4-(7,8-dibenzyloxyquinolin-5-yl)-1-(triisopropylsilyl)pyrrole

: 671788-47-9
bis-3,4-(7,8-dibenzyloxyquinolin-5-yl)pyrrole

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 0.166667h;
DOI:10.1016/j.tet.2003.02.005

Reference yield:

: 1761-61-1
5-bromosalicyclaldehyde

: 671788-47-9
bis-3,4-(7,8-dibenzyloxyquinolin-5-yl)pyrrole

Guidance literature:: Multi-step reaction with 7 steps

1: 97 percent / HNO₃; AcOH / 1 h / 10 - 20 °C

2: 93 percent / peracetic acid; AcOH / 1 h / 20 °C

3: 90 percent / H₂; HCl / methanol; propan-2-ol / 760 Torr

4: HCl / methanol; propan-2-ol / 120 h / 20 °C

5: 1.61 g / K₂CO₃ / dimethylformamide / 24 h / 20 °C

6: Pd(PPh₃)4; Na₂CO₃ / methanol; toluene; H₂O / 65 - 75 °C

7: 0.38 g / nBu₄NF / tetrahydrofuran / 0.17 h / 20 °C

With hydrogenchloride; peracetic acid; tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutyl ammonium fluoride; hydrogen; nitric acid; sodium carbonate; potassium carbonate; acetic acid; In tetrahydrofuran; methanol; water; N,N-dimethyl-formamide; isopropyl alcohol; toluene; 2: Baeyer-Villiger reaction / 6: Suzuki-Miyaura coupling;
DOI:10.1016/j.tet.2003.02.005

Reference yield:

: 671788-48-0
5-bromo-7,8-dibenzyloxyquinoline

: 671788-47-9
bis-3,4-(7,8-dibenzyloxyquinolin-5-yl)pyrrole

Guidance literature:: Multi-step reaction with 2 steps

1: Pd(PPh₃)4; Na₂CO₃ / methanol; toluene; H₂O / 65 - 75 °C

2: 0.38 g / nBu₄NF / tetrahydrofuran / 0.17 h / 20 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutyl ammonium fluoride; sodium carbonate; In tetrahydrofuran; methanol; water; toluene; 1: Suzuki-Miyaura coupling;
DOI:10.1016/j.tet.2003.02.005