2-Cyclohexen-1-one, 2-methyl-5-(2-methyloxiranyl)-, (5S)-

Base Information

Chemical Name:2-Cyclohexen-1-one, 2-methyl-5-(2-methyloxiranyl)-, (5S)-
CAS No.:672898-51-0
Molecular Formula:C10H14O2
Molecular Weight:166.22
Hs Code.:
DSSTox Substance ID:DTXSID40474721
Nikkaji Number:J2.102.027C

Synonyms:672898-51-0;(5S)-2-METHYL-5-(2-METHYLOXIRAN-2-YL)CYCLOHEX-2-EN-1-ONE;2-Cyclohexen-1-one, 2-methyl-5-(2-methyloxiranyl)-, (5S)-;DTXSID40474721;EN300-1196637;(5S)-2-Methyl-5-(2-methyloxiranyl)-2-cyclohexene-1-one

Suppliers and Price of 2-Cyclohexen-1-one, 2-methyl-5-(2-methyloxiranyl)-, (5S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 2-Cyclohexen-1-one, 2-methyl-5-(2-methyloxiranyl)-, (5S)-

Chemical Property:

XLogP3:1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:166.099379685
Heavy Atom Count:12
Complexity:255

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CCC(CC1=O)C2(CO2)C
Isomeric SMILES:CC1=CC[C@@H](CC1=O)C2(CO2)C

Technology Process of 2-Cyclohexen-1-one, 2-methyl-5-(2-methyloxiranyl)-, (5S)-

There total 2 articles about 2-Cyclohexen-1-one, 2-methyl-5-(2-methyloxiranyl)-, (5S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 2244-16-8,6485-40-1
(S)-p-mentha-6,8-dien-2-one

: 672898-51-0
(5S)-2-methyl-5-(2-methyloxiran-2-yl)cyclohex-2-en-1-one

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 - 23 ℃; for 15.0833h; Inert atmosphere; Schlenk technique;
DOI:10.1021/jacs.0c07316

Reference yield:

: 93-59-4
Perbenzoic acid

: 2244-16-8,6485-40-1
(S)-p-mentha-6,8-dien-2-one

: 672898-51-0
(5S)-2-methyl-5-(2-methyloxiran-2-yl)cyclohex-2-en-1-one

Guidance literature:: With chloroform;

Reference yield:

: 672898-51-0
(5S)-2-methyl-5-(2-methyloxiran-2-yl)cyclohex-2-en-1-one

: 2416-94-6
2,3,6-trimethylphenol

Guidance literature:: Multi-step reaction with 2 steps

1: bis(cyclopentadienyl)titanium (III) chloride / tetrahydrofuran / 23 °C / Inert atmosphere

2: [Rh(OH)(cod)]2; tert-Butyl acrylate / benzene-d6 / 24 h / 70 °C / Inert atmosphere

With [Rh(OH)(cod)]2; bis(cyclopentadienyl)titanium (III) chloride; tert-Butyl acrylate; In tetrahydrofuran; benzene-d6;
DOI:10.1021/jacs.5b02254