7-Chlorobicyclo[2.2.1]heptan-2-one

Base Information

• Chemical Name: 7-Chlorobicyclo[2.2.1]heptan-2-one
• CAS No.: 89856-87-1
• Molecular Formula: C₇H₉ClO
• Molecular Weight: 144.601
• NSC Number: 167215
• DSSTox Substance ID: DTXSID10304763
• Mol file: 89856-87-1.mol

Synonyms:89856-87-1;NSC167215;DTXSID10304763;7-chlorobicyclo[2.2.1]heptan-2-one;NSC-167215

Chemical Property of 7-Chlorobicyclo[2.2.1]heptan-2-one

Chemical Property:

• Vapor Pressure: 0.035mmHg at 25°C
• Boiling Point: 241.9°Cat760mmHg
• Flash Point: 100.5°C
• Density: 1.23g/cm³
• XLogP3: 1.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 144.0341926
• Heavy Atom Count: 9
• Complexity: 155

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC2C(C1CC2=O)Cl

Technology Process of 7-Chlorobicyclo[2.2.1]heptan-2-one

There total 14 articles about 7-Chlorobicyclo[2.2.1]heptan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

7-bromobicyclo[2.2.1]heptan-2-one → anti-7-chloro-2-norbornanone (7176-92-3,38537-60-9,89856-87-1)

Guidance literature:

With lithium chloride; In N,N-dimethyl-formamide; for 7h; Heating;

Reference yield:

syn-2-chloro-7-hydroxynorbornane (38537-30-3,38537-32-5,38537-61-0,38537-64-3,98431-04-0) → syn-7-chloro-2-norbornanone (7176-92-3,38537-60-9,89856-87-1)

Guidance literature:

With potassium dichromate; sulfuric acid; water; und Essigsaeure;

DOI:10.1021/jo01360a618

Reference yield:

(+/-)-7anti-chloro-norbornane-2exo-ol (38537-30-3,38537-32-5,38537-61-0,38537-64-3,98431-04-0) → anti-7-chloro-2-norbornanone (7176-92-3,38537-60-9,89856-87-1)

Guidance literature:

With potassium dichromate; sulfuric acid; water; und Essigsaeure;

DOI:10.1021/jo01360a618

upstream raw materials:

syn-2-chloro-7-hydroxynorbornane

(+/-)-7anti-chloro-norbornane-2exo-ol

norborn-2-ene

norbornene

Downstream raw materials:

syn-7-Chlor-nor-campherchinon

anti-7-Chloro-endo-2-tosyloxybicyclo<2.2.1>heptan

anti-7-chloro-exo-2-norbornyl brosylate

anti-7-chloro-endo-2-norbornyl brosylate