2-Cyclohexen-1-one, 2-fluoro-

Base Information

Chemical Name:2-Cyclohexen-1-one, 2-fluoro-
CAS No.:67542-14-7
Molecular Formula:C6H7FO
Molecular Weight:114.11800
Hs Code.:
DSSTox Substance ID:DTXSID50472016
Wikidata:Q82300759

Synonyms:2-fluorocyclohex-2-en-1-one;2-Cyclohexen-1-one, 2-fluoro-;67542-14-7;2-fluorocyclohexenone;2-Fluoro-cyclohex-2-enone;DTXSID50472016;EN300-7600952

Suppliers and Price of 2-Cyclohexen-1-one, 2-fluoro-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 2-Cyclohexen-1-one, 2-fluoro-

Chemical Property:

PSA：17.07000
LogP:1.59280
XLogP3:1.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:114.048093005
Heavy Atom Count:8
Complexity:138

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC=C(C(=O)C1)F

Technology Process of 2-Cyclohexen-1-one, 2-fluoro-

There total 5 articles about 2-Cyclohexen-1-one, 2-fluoro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 122617-93-0
allyl 1-fluoro-2-oxocyclohexanonecarboxylate

: 67542-14-7
fluoro-2 cyclohexene-2 one-1

Guidance literature:: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triphenylphosphine; In acetonitrile; for 2h; Heating;
DOI:10.1246/cl.1999.577 DOI:10.1016/S0040-4020(01)80770-5

Reference yield:

: 5453-93-0
allyl 2-oxocyclohexane-1-carboxylate

: 67542-14-7
fluoro-2 cyclohexene-2 one-1

Guidance literature:: Multi-step reaction with 2 steps

1: 60 percent / NaH, N-fluoro-2,4,6-trimethylpyridinium triflate / tetrahydrofuran / 2 h / 0 °C

2: 56 percent / Pd₂(dba)3CHCl₃, PPh₃ / acetonitrile / 2 h / Heating

With sodium hydride; 1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triphenylphosphine; In tetrahydrofuran; acetonitrile;
DOI:10.1016/S0040-4020(01)80770-5

Reference yield:

: 3242-56-6
2-diazocyclohexanone

: 67542-14-7
fluoro-2 cyclohexene-2 one-1

Guidance literature:: With Phenylselenyl bromide; dihydrogen peroxide; silver fluoride; Yield given. Multistep reaction; 1.) CH₂Cl₂, from 5 to 10 deg C, sonication, 1.5 h, 2.) CH₂Cl₂, sonication, 30 min;
DOI:10.1039/c39920001148