(R)-2-(1,5-Dimethyl-4-hexenyl)-5-methyl-1,4-benzenediol

Base Information

Chemical Name:(R)-2-(1,5-Dimethyl-4-hexenyl)-5-methyl-1,4-benzenediol
CAS No.:69301-25-3
Molecular Formula:C15H22O2
Molecular Weight:234.334
Hs Code.:
DSSTox Substance ID:DTXSID00989023
Nikkaji Number:J18.662G
Wikidata:Q82977823
Metabolomics Workbench ID:168258
Mol file:69301-25-3.mol

Synonyms:69301-25-3;(R)-2-(1,5-Dimethyl-4-hexenyl)-5-methyl-1,4-benzenediol;2-methyl-5-[(2R)-6-methylhept-5-en-2-yl]benzene-1,4-diol;DTXSID00989023;1,4-Benzenediol, 2-(1,5-dimethyl-4-hexenyl)-5-methyl-, (R)-;2-Methyl-5-(6-methylhept-5-en-2-yl)benzene-1,4-diol

Suppliers and Price of (R)-2-(1,5-Dimethyl-4-hexenyl)-5-methyl-1,4-benzenediol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (R)-2-(1,5-Dimethyl-4-hexenyl)-5-methyl-1,4-benzenediol

Chemical Property:

Vapor Pressure:2.4E-06mmHg at 25°C
Boiling Point:380.9°Cat760mmHg
Flash Point:176.4°C
PSA：40.46000
Density:1.025g/cm³
LogP:4.25610
XLogP3:4.7
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:234.161979940
Heavy Atom Count:17
Complexity:256

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(=C(C=C1O)C(C)CCC=C(C)C)O
Isomeric SMILES:CC1=CC(=C(C=C1O)[C@H](C)CCC=C(C)C)O

Technology Process of (R)-2-(1,5-Dimethyl-4-hexenyl)-5-methyl-1,4-benzenediol

There total 12 articles about (R)-2-(1,5-Dimethyl-4-hexenyl)-5-methyl-1,4-benzenediol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 670260-38-5
(R)-(-)-curcuquinone

: 69301-25-3
2-methyl-5-[(2R)-6-methylhept-5-en-2-yl]benzene-1,4-diol

Guidance literature:: (R)-(-)-curcuquinone; With sodium tetrahydroborate; In methanol; at 0 - 20 ℃;

With ammonium chloride; In methanol; water; at 20 ℃;
DOI:10.1039/c2cc32176a

Reference yield:

: 5-((R)-1,5-Dimethyl-hex-4-enyl)-2-methyl-cyclohex-2-ene-1,4-dione

: 69301-25-3
2-methyl-5-[(2R)-6-methylhept-5-en-2-yl]benzene-1,4-diol

Guidance literature:: With triethylamine; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1021/jo061730d

Reference yield:

: 915235-16-4
6-hydroxy-4-((R)-6-methylhept-5-en-2-yl)cyclohex-2-enone

: 69301-25-3
2-methyl-5-[(2R)-6-methylhept-5-en-2-yl]benzene-1,4-diol

Guidance literature:: Multi-step reaction with 6 steps

1.1: Mg / diethyl ether / 2 h / 20 °C

1.2: 95 percent / diethyl ether / 12 h / 20 °C

2.1: 85 percent / pyridine / 12 h / 20 °C

3.1: 80 percent / pyridinium chlorochromate / CH₂Cl₂ / 8 h / 20 °C

4.1: K₂CO₃ / methanol / 0.5 h

5.1: Dess-Martin periodinane / CH₂Cl₂ / 1 h / 20 °C

6.1: Et₃N / CH₂Cl₂ / 3 h / 20 °C

With pyridine; potassium carbonate; Dess-Martin periodane; magnesium; triethylamine; pyridinium chlorochromate; In methanol; diethyl ether; dichloromethane; 1.2: Grignard reaction / 5.1: Dess-Martin oxidation;
DOI:10.1021/jo061730d