1-Pyrenyldiazomethane

Base Information

Chemical Name:1-Pyrenyldiazomethane
CAS No.:78377-23-8
Molecular Formula:C17H10 N2
Molecular Weight:242.2747
Hs Code.:2927000090
DSSTox Substance ID:DTXSID70999730
Nikkaji Number:J408.850F
Mol file:78377-23-8.mol

Synonyms:1-diazomethylpyrene;1-pyrenyldiazomethane;PDAM

Suppliers and Price of 1-Pyrenyldiazomethane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
PDAM
25mg
$ 280.00

Sigma-Aldrich
PDAM for HPLC derivatization
25mg
$ 404.00

Chem-Impex
PDAM,forHPLCderivatization,≥70%(HPLC),suitableforHematology&Histology ≥70%(HPLC)
25MG
$ 433.31

American Custom Chemicals Corporation
1-PYRENYLDIAZOMETHANE 95.00%
5MG
$ 500.42

Total 16 raw suppliers

Chemical Property of 1-Pyrenyldiazomethane

Chemical Property:

Melting Point:112℃
PSA：37.39000
LogP:4.31376
Storage Temp.:−20°C
XLogP3:4.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:242.084398327
Heavy Atom Count:19
Complexity:398

Purity/Quality:

98%Min ^*data from raw suppliers

PDAM ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1=CC2=C3C(=C1)C=CC4=C(C=CC(=C43)C=C2)C=[N+]=[N-]
Uses PDAM is a fluorescent diazoalkane that is useful as an HPLC derivatization reagent for carboxylic acid detection. Dyes and metabolites.

Technology Process of 1-Pyrenyldiazomethane

There total 2 articles about 1-Pyrenyldiazomethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 76465-53-7
1-pyrenecarboxaldehyde hydrazone

: 78377-23-8
pyrenyl-1-diazomethane

Guidance literature:: With potassium hydroxide; mercury(II) oxide; In diethyl ether;
DOI:10.1016/S0040-4039(00)95811-8

Reference yield:

: 3029-19-4
pyrene-1-aldehyde

: 78377-23-8
pyrenyl-1-diazomethane

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / N₂H₄*H₂O / ethanol / 3 h / Ambient temperature

2: 85 percent / MnO₂ / diethyl ether / 1.33 h / Ambient temperature

With manganese(IV) oxide; hydrazine hydrate; In diethyl ether; ethanol;
DOI:10.1021/ac00170a017