1,1,2,3,3-Pentafluoro-3-(trifluoromethoxy)prop-1-ene

Base Information

• Chemical Name: 1,1,2,3,3-Pentafluoro-3-(trifluoromethoxy)prop-1-ene
• CAS No.: 67641-44-5
• Molecular Formula: C4F8O
• Molecular Weight: 216.02900
• Hs Code.: 2909199090
• DSSTox Substance ID: DTXSID00382474
• Mol file: 67641-44-5.mol

Synonyms:67641-44-5;Octafluoro-3-methoxyprop-1-ene;1,1,2,3,3-pentafluoro-3-(trifluoromethoxy)prop-1-ene;perfluoro-3-methoxy-propene;SCHEMBL6668427;1-Propene, 1,1,2,3,3-pentafluoro-3-(trifluoromethoxy)-;DTXSID00382474;QPYXRHPMKLWCEA-UHFFFAOYSA-N;AKOS025310442;A835838

Chemical Property of 1,1,2,3,3-Pentafluoro-3-(trifluoromethoxy)prop-1-ene

Chemical Property:

• Vapor Pressure: 1100mmHg at 25°C
• Boiling Point: 14.4oC at 760 mmHg
• PSA: 9.23000
• Density: 1.567g/cm3
• LogP: 3.19320
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 9
• Rotatable Bond Count: 2
• Exact Mass: 215.98213992
• Heavy Atom Count: 13
• Complexity: 211

Purity/Quality:

99% ^*data from raw suppliers

Octafluoro-3-methoxyprop-1-ene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=C(F)F)(C(OC(F)(F)F)(F)F)F

Technology Process of 1,1,2,3,3-Pentafluoro-3-(trifluoromethoxy)prop-1-ene

There total 3 articles about 1,1,2,3,3-Pentafluoro-3-(trifluoromethoxy)prop-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

Carbonyl fluoride (353-50-4) + perfluoroallylfluorosulphate (67641-28-5) → 1,1,2,3,3-pentafluoro-3-(perfluoromethoxy)prop-1-ene (67641-44-5)

Guidance literature:

Carbonyl fluoride; With potassium fluoride; In diethylene glycol dimethyl ether; at 5 ℃; for 2h; Autoclave;

perfluoroallylfluorosulphate; In diethylene glycol dimethyl ether; at 5 - 20 ℃; for 5h; under 5320.36 Torr; Autoclave;

DOI:10.3390/molecules16086512

Reference yield:

Perfluor-γ-methoxybuttersaeuremethylester (39187-40-1) → 1,1,2,3,3-pentafluoro-3-(perfluoromethoxy)prop-1-ene (67641-44-5)

Guidance literature:

Multistep reaction;

Reference yield:

→ 1,1,2,3,3-pentafluoro-3-(perfluoromethoxy)prop-1-ene (67641-44-5)

Guidance literature:

COF2, CsF, CF2=CF-CF2-OSO2F;

upstream raw materials:

Perfluor-γ-methoxybuttersaeuremethylester

Carbonyl fluoride

perfluoroallylfluorosulphate

Downstream raw materials:

1,2,3,3,3-pentafluoro-1-(perfluoromethoxy)prop-1-ene