Benzoic acid, 2-(8,11-heptadecadienyl)-6-hydroxy-, (Z,Z)-

Base Information

Chemical Name:Benzoic acid, 2-(8,11-heptadecadienyl)-6-hydroxy-, (Z,Z)-
CAS No.:141545-69-9
Deprecated CAS:72429-66-4
Molecular Formula:C24H36 O3
Molecular Weight:372.5408
Hs Code.:
Mol file:141545-69-9.mol

Synonyms:Pelandjauic acid;[(9Z,15E)-heptadeca-9,15-dien-7-yl] 2-hydroxybenzoate;Benzoic acid, 2-(8,11-heptadecadienyl)-6-hydroxy-, (Z,Z)-;141545-69-9;AKOS040735865

Suppliers and Price of Benzoic acid, 2-(8,11-heptadecadienyl)-6-hydroxy-, (Z,Z)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Arctom
Pelandjauicacid
5mg
$ 512.00

Total 2 raw suppliers

Chemical Property of Benzoic acid, 2-(8,11-heptadecadienyl)-6-hydroxy-, (Z,Z)-

Chemical Property:

Vapor Pressure:7.17E-10mmHg at 25°C
Melting Point:25 - 26 °C (acetone)
Boiling Point:480.9°C at 760 mmHg
Flash Point:181.3°C
PSA：46.53000
Density:0.986g/cm³
LogP:6.97080
XLogP3:8.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:15
Exact Mass:372.26644501
Heavy Atom Count:27
Complexity:427

Purity/Quality:

98% ^*data from raw suppliers

Pelandjauicacid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCC(CC=CCCCCC=CC)OC(=O)C1=CC=CC=C1O
Isomeric SMILES:CCCCCCC(C/C=C\CCCC/C=C/C)OC(=O)C1=CC=CC=C1O

Technology Process of Benzoic acid, 2-(8,11-heptadecadienyl)-6-hydroxy-, (Z,Z)-

There total 13 articles about Benzoic acid, 2-(8,11-heptadecadienyl)-6-hydroxy-, (Z,Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 173473-62-6
6-methoxy-2-(heptadecadien-(8c.11c)-yl)-benzoic acid

: 141545-69-9
6-(8′Z,11′Z)-heptadecadienyl-salicylic acid

Guidance literature:: With aluminium(III) iodide; (+)-limonene; In carbon disulfide; 1.) r.t., 10 min, 2.) reflux, 30 min;

Reference yield:

: 10160-26-6
9-(2-tetrahydropyranyloxy)-1-nonyne

: 141545-69-9
6-(8′Z,11′Z)-heptadecadienyl-salicylic acid

Guidance literature:: Multi-step reaction with 12 steps

1: n-BuLi / tetrahydrofuran; hexane / 1.) 0 deg C, 30 min, 2.) r.t., 70 min

2: p-TsOH*H₂O / methanol / 1 h / Ambient temperature

3: 99 percent / pyridine / 3.5 h / Ambient temperature

4: 73 percent / dichloromaleic anhydride / 200 °C

5: 99 percent / 2 M KOH / ethanol / 19 h / Heating

6: 72 percent / CBr₄, PPh₃ / CH₂Cl₂ / 6 h / Ambient temperature

7: n-BuLi / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 1.) -78 deg C, 3.5 h, 2.) -78 deg C to r.t., 17 h

8: p-TsOH*H₂O / methanol / 1 h / Heating

9: 68 percent / CBr₄, PPh₃ / diethyl ether; CH₂Cl₂ / 1.) 0 deg C, 1 h, 2.) r.t., 17 h

10: 1.) EtMgBr, 2.) CuCN / 1.) THF, reflux, 1 h; r.t., 15 min, 2.) 0 deg C, 30 min; r.t., 15 h

11: H₂, quinoline / 5percent Pd/BaSO₄ / pyridine / 1.92 h / 750.06 Torr / Ambient temperature

12: 63 percent / AlI₃, (+)-limonene / CS₂ / 1.) r.t., 10 min, 2.) reflux, 30 min

With pyridine; quinoline; potassium hydroxide; aluminium(III) iodide; n-butyllithium; dichloromaleic acid anhydride; carbon tetrabromide; ethylmagnesium bromide; hydrogen; (+)-limonene; toluene-4-sulfonic acid; triphenylphosphine; Pd-BaSO₄; In tetrahydrofuran; pyridine; methanol; carbon disulfide; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; ethanol; hexane; dichloromethane;

Reference yield:

: 10160-28-8
8-nonyn-1-ol

: 141545-69-9
6-(8′Z,11′Z)-heptadecadienyl-salicylic acid

Guidance literature:: Multi-step reaction with 13 steps

1: p-TsOH*H₂O / 2 h / Ambient temperature

2: n-BuLi / tetrahydrofuran; hexane / 1.) 0 deg C, 30 min, 2.) r.t., 70 min

3: p-TsOH*H₂O / methanol / 1 h / Ambient temperature

4: 99 percent / pyridine / 3.5 h / Ambient temperature

5: 73 percent / dichloromaleic anhydride / 200 °C

6: 99 percent / 2 M KOH / ethanol / 19 h / Heating

7: 72 percent / CBr₄, PPh₃ / CH₂Cl₂ / 6 h / Ambient temperature

8: n-BuLi / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 1.) -78 deg C, 3.5 h, 2.) -78 deg C to r.t., 17 h

9: p-TsOH*H₂O / methanol / 1 h / Heating

10: 68 percent / CBr₄, PPh₃ / diethyl ether; CH₂Cl₂ / 1.) 0 deg C, 1 h, 2.) r.t., 17 h

11: 1.) EtMgBr, 2.) CuCN / 1.) THF, reflux, 1 h; r.t., 15 min, 2.) 0 deg C, 30 min; r.t., 15 h

12: H₂, quinoline / 5percent Pd/BaSO₄ / pyridine / 1.92 h / 750.06 Torr / Ambient temperature

13: 63 percent / AlI₃, (+)-limonene / CS₂ / 1.) r.t., 10 min, 2.) reflux, 30 min

With pyridine; quinoline; potassium hydroxide; aluminium(III) iodide; n-butyllithium; dichloromaleic acid anhydride; carbon tetrabromide; ethylmagnesium bromide; hydrogen; (+)-limonene; toluene-4-sulfonic acid; triphenylphosphine; Pd-BaSO₄; In tetrahydrofuran; pyridine; methanol; carbon disulfide; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; ethanol; hexane; dichloromethane;