Anthracene, 9-[diazo(4-ethynyl-2,6-dimethylphenyl)methyl]-10-phenyl-

Base Information

Chemical Name:Anthracene, 9-[diazo(4-ethynyl-2,6-dimethylphenyl)methyl]-10-phenyl-
CAS No.:677351-16-5
Molecular Formula:C31H22N2
Molecular Weight:422.529
Hs Code.:

Synonyms:

Suppliers and Price of Anthracene, 9-[diazo(4-ethynyl-2,6-dimethylphenyl)methyl]-10-phenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 3 raw suppliers

Chemical Property of Anthracene, 9-[diazo(4-ethynyl-2,6-dimethylphenyl)methyl]-10-phenyl-

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Anthracene, 9-[diazo(4-ethynyl-2,6-dimethylphenyl)methyl]-10-phenyl-

There total 8 articles about Anthracene, 9-[diazo(4-ethynyl-2,6-dimethylphenyl)methyl]-10-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 677351-13-2
[9-(10-phenylanthryl)](2,6-dimethyl-4-trimethylsilylethynylphenyl)diazomethane

: 677351-16-5
9-[diazo-(4-ethynyl-2,6-dimethyl-phenyl)-methyl]-10-phenyl-anthracene

Guidance literature:: With sodium hydroxide; tert-butyl alcohol; at 20 ℃;
DOI:10.1021/ol049877j

Reference yield:

: 54458-81-0
10-Phenylanthracene-9-carboxaldehyde

: 677351-16-5
9-[diazo-(4-ethynyl-2,6-dimethyl-phenyl)-methyl]-10-phenyl-anthracene

Guidance literature:: Multi-step reaction with 7 steps

1.1: n-BuLi / hexane; diethyl ether / 3 h / -78 °C

1.2: 67 percent / tetrahydrofuran; hexane; diethyl ether / 20 °C

2.1: 97 percent / HCl gas / methanol; benzene / 1 h

3.1: 76 percent / AgBF₄; CH₃Cl / CH₂Cl₂ / Heating

4.1: N₂O₄; NaOAc / CCl₄ / -20 - 20 °C

5.1: 421 mg / t-BuOK / tetrahydrofuran

6.1: 20 percent / CuI; (PPh₃)2PdCl₂; Et₃N / 35 °C

7.1: 98 percent / aq. NaOH; t-BuOH / 20 °C

With hydrogenchloride; bis-triphenylphosphine-palladium(II) chloride; sodium hydroxide; copper(l) iodide; silver tetrafluoroborate; n-butyllithium; methylene chloride; potassium tert-butylate; sodium acetate; dinitrogen tetraoxide; triethylamine; tert-butyl alcohol; In tetrahydrofuran; methanol; tetrachloromethane; diethyl ether; hexane; dichloromethane; benzene; 6.1: Sonogashira coupling;
DOI:10.1021/ol049877j

Reference yield:

: 206559-43-5,260355-37-1
5-bromo-2-iodo-1,3-dimethyl-benzene

: 677351-16-5
9-[diazo-(4-ethynyl-2,6-dimethyl-phenyl)-methyl]-10-phenyl-anthracene

Guidance literature:: Multi-step reaction with 7 steps

1.1: n-BuLi / hexane; diethyl ether / 3 h / -78 °C

1.2: 67 percent / tetrahydrofuran; hexane; diethyl ether / 20 °C

2.1: 97 percent / HCl gas / methanol; benzene / 1 h

3.1: 76 percent / AgBF₄; CH₃Cl / CH₂Cl₂ / Heating

4.1: N₂O₄; NaOAc / CCl₄ / -20 - 20 °C

5.1: 421 mg / t-BuOK / tetrahydrofuran

6.1: 20 percent / CuI; (PPh₃)2PdCl₂; Et₃N / 35 °C

7.1: 98 percent / aq. NaOH; t-BuOH / 20 °C

With hydrogenchloride; bis-triphenylphosphine-palladium(II) chloride; sodium hydroxide; copper(l) iodide; silver tetrafluoroborate; n-butyllithium; methylene chloride; potassium tert-butylate; sodium acetate; dinitrogen tetraoxide; triethylamine; tert-butyl alcohol; In tetrahydrofuran; methanol; tetrachloromethane; diethyl ether; hexane; dichloromethane; benzene; 6.1: Sonogashira coupling;
DOI:10.1021/ol049877j