1-diphenylphosphanyl-N-methylmethanethioamide

Base Information

Chemical Name:1-diphenylphosphanyl-N-methylmethanethioamide
CAS No.:14633-76-2
Molecular Formula:C14H14 N P S
Molecular Weight:259.312
Hs Code.:
NSC Number:346106
DSSTox Substance ID:DTXSID70397777
Nikkaji Number:J1.886.970E
Mol file:14633-76-2.mol

Synonyms:14633-76-2;1-diphenylphosphanyl-N-methylmethanethioamide;NSC346106;DTXSID70397777;NSC-346106;alpha-(Methylamino)-alpha-(diphenylphosphino)methanethione

Suppliers and Price of 1-diphenylphosphanyl-N-methylmethanethioamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of 1-diphenylphosphanyl-N-methylmethanethioamide

Chemical Property:

Vapor Pressure:1.25E-05mmHg at 25°C
Boiling Point:368.7°C at 760 mmHg
Flash Point:176.8°C
XLogP3:3.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:259.05845762
Heavy Atom Count:17
Complexity:227

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CNC(=S)P(C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of 1-diphenylphosphanyl-N-methylmethanethioamide

There total 1 articles about 1-diphenylphosphanyl-N-methylmethanethioamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14633-76-2
1-(diphenylphosphino)-N-methylthioformamide

Guidance literature:: Diphenylphosphin, Methylisothiocyanat in sd. Bzl.;
DOI:10.1002/zaac.19673510104

Reference yield: 93.0%

: 69462-29-9
bis(tetrahydrothiophene)gold(I) perchlorate

: 14633-76-2
1-(diphenylphosphino)-N-methylthioformamide

: 565430-49-1
Au(diphenylphosphinothioformamide)2ClO₄

Guidance literature:: In dichloromethane; ligand was added to CH2Cl2 soln. of Au-complex, stirred for 1 h; solvent was evapd., Et2O was added; elem. anal.;
DOI:10.1039/b211865c

Reference yield: 90.0%

: di(rhodium)tetracarbonyl dichloride

: 14633-76-2
1-(diphenylphosphino)-N-methylthioformamide

: RhCl(CO)((C₆H₅)2PC(S)NHCH₃)2*0.05C₆H₅CH₃

Guidance literature:: In toluene; N2-atmosphere; molar ratio Rh:P=1:2.1, stirring for 2 h; pentane addn., collection (filtration), washing (pentane, Et2O), drying (vac.); elem. anal.;
DOI:10.1016/S0020-1693(00)88330-9